Malodor reduction compositions

ABSTRACT

The present invention relates to malodor reduction compositions and methods of making and using same. The malodor reduction compositions are suitable for use in a variety of applications, including use in consumer products, for example, air freshening compositions, laundry detergents, fabric enhancers, surface cleaners, beauty care products, dish care products, diapers, feminine protection articles, and plastic films for garbage bags. Such malodor control technologies do not unduely interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.

FIELD OF THE INVENTION

The present invention relates to malodor reduction compositions and methods of making and using same.

BACKGROUND OF THE INVENTION

Unscented or scented products are desired by consumers as they may be considered more natural and discreet than scented products. Manufacturers of unscented or scented products for controlling malodors rely on malodor reduction ingredients or other technologies (e.g. filters) to reduce malodors. However, effectively controlling malodors, for example, amine-based malodors (e.g. fish and urine), thiol and sulfide-based malodors (e.g. garlic and onion), C₂-C₁₂ carboxylic acid based malodors (e.g. body and pet odor), indole based malodors (e.g. fecal and bad breath), short chain fatty aldehyde based malodors (e.g. grease) and geosmin based malodors (e.g. mold/mildew) may be difficult, and the time required for a product to noticeably reduce malodors may create consumer doubt as to the product's efficacy on malodors. Often times, manufacturers incorporate scented perfumes to help mask these difficult malodors.

Unfortunately, malodor control technologies typically cover up the malodor with a stronger scent and thus interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology. Thus, limited nature of the current malodor control technologies is extremely constraining. Thus what is needed is a broader palette of malodor control technologies so the perfume community can deliver the desired level of character in a greater number of situations/applications. Surprisingly, Applicants recognized that in addition to blocking a malodor's access to a sensory cell, in order to achieve the desired goal, a malodor control technology must leave such sensor cell open to other molecules, for example scent molecules. Thus, the malodor control technologies disclosed herein do not unduely interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.

SUMMARY OF THE INVENTION

The present invention relates to malodor reduction compositions and methods of making and using same. The malodor reduction compositions are suitable for use in a variety of applications, including use in consumer products, for example, air freshening compositions, laundry detergents, fabric enhancers, surface cleaners, beauty care products, dish care products, diapers, feminine protection articles, and plastic films for garbage bags. Such malodor control technologies do not unduely interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.

DETAILED DESCRIPTION OF THE INVENTION

As used herein “MORV” is the calculated malodor reduction value for a subject material. A material's MORV indicates such material's ability to decrease or even eliminate the perception of one or more malodors. For purposes of the present application, a material's MORV is calculated in accordance with method found in the test methods section of the present application.

As used herein “consumer product” means baby care, beauty care, fabric & home care, family care, feminine care, health care, snack and/or beverage products or devices. Such products include but are not limited to plastic films garbage bags, storage bags, storage wraps, diapers, bibs, wipes, garments, textiles including sheets and towels, composters; products for and/or methods relating to treating hair (human, dog, and/or cat), including, bleaching, coloring, dyeing, conditioning, wet or dry shampooing, styling, scalp treatments; deodorants and antiperspirants; personal cleansing; cosmetics; skin care including application of creams, lotions, fine fragrances and other topically applied products for consumer use; and shaving products, products for and/or methods relating to treating fabrics, hard surfaces and any other surfaces in the area of fabric and home care, including: air care including air filtration, car care, dishwashing, fabric conditioning (including softening), laundry detergency, laundry and rinse additive and/or care, hard surface cleaning and/or treatment, towel bowl cleaners and other cleaning and/or malodor treatments for consumer, agricultural, industrial or institutional use; products and/or methods relating to bath tissue, facial tissue, paper handkerchiefs, and/or paper towels; tampons, feminine napkins; products and/or methods relating to oral care including toothpastes, tooth gels, tooth rinses, denture adhesives, tooth whitening.

As used herein “energized system”, refers to a system that operates by using an electrical and/or mechanical energy source such as a battery or electrical wall outlet to emit the malodor reduction composition. Examples of such devices include but are limited to liquid electric pluggable type air freshening devices.

As used herein, “malodor” refers to compounds generally offensive or unpleasant to most people, such as the complex odors associated with bowel movements.

As used herein, “neutralize” or “neutralization” refers to the ability of a compound or product to reduce or eliminate malodorous compounds. Odor neutralization may be partial, affecting only some of the malodorous compounds in a given context, or affecting only part of a malodorous compound. A malodorous compound may be neutralized by chemical reaction resulting in a new chemical entity, by sequestration, by chelation, by association, or by any other interaction rendering the malodorous compound less malodorous or non-malodorous. Neutralization is distinguishable from odor masking or odor blocking by a change in the malodorous compound, as opposed to a change in the ability to perceive the malodor without any corresponding change in the condition of the malodorous compound. Malodor neutralization provides a sensory and analytically measurable (e.g. gas chromatograph) malodor reduction. Thus, if a malodor reduction composition delivers genuine malodor neutralization, the composition will reduce malodors in the vapor and/or liquid phase.

As used herein, “non-energized” refers to a system that emits a targeted active passively or without the need for an electrical energy source. Handheld aerosol sprayers and traditional trigger/pump sprayers are considered non-energized systems.

As used herein, “odor blocking” refers to the ability of a compound to dull the human sense of smell.

As used herein, “odor masking” refers to the ability of a compound with a non-offensive or pleasant smell that is dosed such that it limits the ability to sense a malodorous compound. Odor-masking may involve the selection of compounds which coordinate with an anticipated malodor to change the perception of the overall scent provided by the combination of odorous compounds.

As used herein, the terms “a” and “an” mean “at least one”.

As used herein, the terms “include”, “includes” and “including” are meant to be non-limiting.

Unless otherwise noted, all component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.

All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated.

It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.

Malodor Reduction Materials

Codes A = Vapor Pressure >0.1 torr B = Vapor Pressure is between 0.01 torr and 0.1 torr C = ClogP <3 D = ClogP >3 E = Probability of Ingredient Color Instability = 0% F = Probability of Ingredient Color Instability <71% G = Odor Detection Threshold less than p.ol = 8 H = Odor Detection Threshold greater than p.ol = 8 I = Melamine formaldehyde PMC Headspace Response Ratio greater than or equal to 10 J = Melamine formaldehyde PMC leakage less than or equal to 5% K = Log of liquid dish neat product liquid-air partition coefficient greater than or equal to −7 L = Log of liquid dish neat product liquid-air partition coefficient greater than or equal to −5

TABLE 1 List of materials with at least one MORV from 1 to 5 Num- CAS Comment ber Material Name Number Code 1 2-ethylhexyl (Z)-3-(4- 5466-77-3 DEFHJ methoxyphenyl)acrylate 2 2,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4 DFHJ 5,6,7,8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane 3 1,1-dimethoxynon-2-yne 13257-44-8 ACEFHJK 4 para-Cymen-8-ol 1197-01-9 BCGIJK 7 3-methoxy-7,7-dimethyl-10- 216970-21-7 BDEFHJK methylenebicyclo[4.3.1]decane 9 Methoxycyclododecane 2986-54-1 DEFHJK 10 1,1-dimethoxycyclododecane 950-33-4 DEFHJK 11 (Z)-tridec-2-enenitrile 22629-49-8 DEFHJK 13 Oxybenzone 131-57-7 DEFGJ 14 Oxyoctaline formate 65405-72-3 DFHJK 16 4-methyl-1-oxaspiro[5.5]undecan-4- 57094-40-3 CFGIJK ol 17 7-methyl-2H-benzo[b][1,4]dioxepin- 28940-11-6 CGIK 3(4H)-one 18 1,8-dioxacycloheptadecan-9-one 1725-01-5 DGJ 21 4-(tert-pentyl)cyclohexan-1-one 16587-71-6 ADFGIJKL 22 o-Phenyl anisol 86-26-0 DEFHJK 23 3a,5,6,7,8,8b-hexahydro- 823178-41-2 DEFHJK 2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-1,3-dioxole 25 7-isopropyl-8,8-dimethyl-6,10- 62406-73-9 BDEFHIJK dioxaspiro[4.5]decane 28 Octyl 2-furoate 39251-88-2 DEFHJK 29 Octyl acetate 112-14-1 BDEFHJKL 30 octanal propylene glycol acetal 74094-61-4 BDEFHJKL 31 Octanal 124-13-0 ACHIKL 32 Octanal dimethyl acetal 10022-28-3 ACEFGJKL 33 Myrcene 123-35-3 ADEFGIKL 34 Myrcenol 543-39-5 BCEFGIJK 35 Myrcenyl acetate 1118-39-4 ADEFGJK 36 Myristaldehyde 124-25-4 DFHJK 37 Myristicine 607-91-0 CGJK 38 Myristyl nitrile 629-63-0 DEFHJK 39 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJK octahydronaphthalen-1-ol 42 Ocimenol 5986-38-9 BCHIJK 43 Ocimenol 28977-58-4 BCHIJK 47 Nopyl acetate 128-51-8 DEFHJK 48 Nootkatone 4674-50-4 DHJK 49 Nonyl alcohol 143-08-8 BDEFGIJKL 50 Nonaldehyde 124-19-6 ADHIKL 52 12-methyl-14-tetradec-9-enolide 223104-61-8 DFHJK 57 N-ethyl-p-menthane-3-carboxamide 39711-79-0 DEFGIJK 61 1-(3-methylbenzofuran-2-yl)ethan-1- 23911-56-0 CEFHIK one 62 2-methoxynaphthalene 93-04-9 BDEFHK 63 Nerolidol 7212-44-4 DEFHJK 64 Nerol 106-25-2 BCHIK 65 1-ethyl-3- 31996-78-8 ACEFHIJKL methoxytricyclo[2.2.1.02,6]heptane 67 Methyl (E)-non-2-enoate 111-79-5 ADEFHJKL 68 10-isopropyl-2,7-dimethyl-1- 89079-92-5 BDEFHIJK oxaspiro[4.5]deca-3,6-diene 69 2-(2-(4-methylcyclohex-3-en-1- 95962-14-4 DHJK yl)propyl)cyclopentan-1-one 70 Myrtenal 564-94-3 ACFHIJKL 71 (E)-4-(2,2,3,6- 54992-90-4 BDEFHIJK tetramethylcyclohexyl)but-3-en-2- one 74 Myraldyl acetate 53889-39-7 DHJK 75 Musk tibetine 145-39-1 DHIJ 76 1,7-dioxacycloheptadecan-8-one 3391-83-1 DGJ 77 Musk ketone 81-14-1 DHJ 78 Musk ambrette 83-66-9 DHIJ 79 3-methylcyclopentadecan-1-one 541-91-3 DEFHJK 80 (E)-3-methylcyclopentadec-4-en-1- 82356-51-2 DHJK one 82 3-methyl-4-phenylbutan-2-ol 56836-93-2 BCEFHIK 83 1-(4-isopropylcyclohexyl)ethan-1-ol 63767-86-2 BDEFHIJK 85 Milk Lactone 72881-27-7 DEFHJK 91 Methyl octine carbonate 111-80-8 BDEFHKL 92 Methyl octyl acetaldehyde 19009-56-4 ADFHJKL 93 6,6-dimethoxy-2,5,5-trimethylhex-2- 67674-46-8 ACHIJKL ene 98 Methyl phenylethyl carbinol 2344-70-9 BCEFHIK 100 Methyl stearate 112-61-8 DEFHJ 101 Methyl nonyl acetaldehyde dimethyl 68141-17-3 BDEFHJK acetal 102 Methyl nonyl ketone 112-12-9 BDFHJKL 103 Methyl nonyl acetaldehyde 110-41-8 BDFHJK 104 Methyl myristate 124-10-7 DEFHJK 105 Methyl linoleate 112-63-0 DEFHJ 106 Methyl lavender ketone 67633-95-8 CFHJK 108 Methyl isoeugenol 93-16-3 ACEFHK 109 Methyl hexadecanoate 112-39-0 DEFHJK 110 Methyl eugenol 93-15-2 ACEFHK 112 Methyl epijasmonate 1211-29-6 CHJK 113 Methyl dihydrojasmonate 24851-98-7 DFHJK 114 Methyl diphenyl ether 3586-14-9 DEFHJK 117 Methyl cinnamate 103-26-4 BCEFHK 119 Methyl chavicol 140-67-0 ADEFHK 120 Methyl beta-naphthyl ketone 93-08-3 CEFHK 122 Methyl 2-octynoate 111-12-6 ACEFHKL 123 Methyl alpha-cyclogeranate 28043-10-9 ACHIJKL 126 Methoxycitronellal 3613-30-7 ACFGIJK 128 Menthone 1,2-glycerol ketal 67785-70-0 CEFHJ (racemic) 130 Octahydro-1H-4,7-methanoindene-1- 30772-79-3 BCFHIJKL carbaldehyde 134 3-(3-(tert-butyl)phenyl)-2- 62518-65-4 BDHJK methylpropanal 135 (E)-4-(4,8-dimethylnona-3,7-dien-1- 38462-23-6 DEFHJK yl)pyridine 137 (E)-trideca-3,12-dienenitrile 134769-33-8 DEFHJK 140 2,2-dimethyl-3-(m-tolyl)propan-1-ol 103694-68-4 CEFHIJK 141 2,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJK tetrahydroindeno[1,2-d][1,3]dioxine 142 Maceal 67845-30-1 BDFHJK 143 4-(4-hydroxy-4- 31906-04-4 CHJ methylpentyl)cyclohex-3-ene-1- carbaldehyde 145 l-Limonene 5989-54-8 ADEFGIJKL 146 (Z)-3-hexen-1-yl-2-cyclopenten-1- 53253-09-1 BDHK one 148 Linalyl octanoate 10024-64-3 DEFHJ 149 Linalyl isobutyrate 78-35-3 BDHJK 152 Linalyl benzoate 126-64-7 DFHJ 153 Linalyl anthranilate 7149-26-0 DFHJ 155 Linalool oxide (furanoid) 60047-17-8 BCHIJK 156 linalool oxide 1365-19-1 CGIJK 158 (2Z,6E)-3,7-dimethylnona-2,6- 61792-11-8 BDEFHJK dienenitrile 159 3-(4-methylcyclohex-3-en-1- 6784-13-0 ACFHIJK yl)butanal 161 (2,5-dimethyl-1,3-dihydroinden-2- 285977-85-7 CEFHJK yl)methanol 162 3-(4-(tert-butyl)phenyl)-2- 80-54-6 BDHJK methylpropanal 167 (E)-1-(1-methoxypropoxy)hex-3-ene 97358-54-8 ACEFGJKL 168 Leaf acetal 88683-94-7 ACEFGJKL 170 l-Carveol 2102-58-1 BCHIJK 174 Lauryl alcohol 112-53-8 DEFGJK 175 Lauryl acetate 112-66-3 DEFHJK 176 Lauric acid 143-07-7 DEFHJ 177 Lactojasmone 7011-83-8 BDEFHIJKL 178 Lauraldehyde 112-54-9 BDFHJK 179 3,6-dimethylhexahydrobenzofuran- 92015-65-1 BCEFHIJKL 2(3H)-one 182 4-(1-ethoxyvinyl)-3,3,5,5- 36306-87-3 BDFHIJK tetramethylcyclohexan-1-one 183 Khusimol 16223-63-5 CEFHJK 184 5-(sec-butyl)-2-(2,4- 117933-89-8 DEFHJ dimethylcyclohex-3-en-1-yl)-5- methyl-1,3-dioxane 185 (1-methyl-2-((1,2,2- 198404-98-7 DEFHJK trimethylbicyclo[3.1.0]hexan-3- yl)methyl)cyclopropyl)methanol 186 2-propylheptanenitrile 208041-98-9 ADEFHIJKL 187 (E)-6-(pent-3-en-1-yl)tetrahydro-2H- 32764-98-0 BCFHIKL pyran-2-one 189 2-hexylcyclopentan-1-one 13074-65-2 BDFHJKL 190 2-methyl-4-phenyl-1,3-dioxolane 33941-99-0 BCEFGIK 192 2,6,9,10-tetramethyl-1- 71078-31-4 BDEFHIJK oxaspiro(4.5)deca-3,6-diene 193 Isopulegol 89-79-2 BCEFHIJKL 195 Isopropyl palmitate 142-91-6 DEFHJ 196 Isopropyl myristate 110-27-0 DEFHJK 197 Isopropyl dodecanoate 10233-13-3 DEFHJK 199 Isopimpinellin 482-27-9 CFGJ 206 Iso3-methylcyclopentadecan-1-one 3100-36-5 DEFGJK 208 Isomenthone 491-07-6 ADEFGIJKL 209 Isojasmone 95-41-0 BDFHJKL 210 Isomenthone 36977-92-1 ADEFGIJKL 211 Isohexenyl cyclohexenyl 37677-14-8 DFHJK carboxaldehyde 212 Isoeugenyl benzyl ether 120-11-6 DFHJ 215 1-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2 DHJK 1,2,3,4,5,6,7,8-octahydronaphthalen- 2-yl)ethan-1-one 218 Isocyclocitral 1335-66-6 ACFHIJKL 221 Isobutyl quinoline 65442-31-1 DEFHJK 227 Isobornylcyclohexanol 68877-29-2 DEFHJK 228 Isobornyl propionate 2756-56-1 BDEFHIJK 229 Isobornyl isobutyrate 85586-67-0 BDEFHIJK 230 Isobornyl cyclohexanol 66072-32-0 DEFHJK 231 Isobornyl acetate 125-12-2 ADEFHIJKL 233 Isobergamate 68683-20-5 DEFHJK 234 Isoamyl undecylenate 12262-03-2 DEFHJK 238 Isoamyl laurate 6309-51-9 DEFHJK 242 Isoambrettolide 28645-51-4 DGJ 243 Irisnitrile 29127-83-1 ADEFHKL 244 Indolene 68527-79-7 DEFHJ 246 Indol/Hydroxycitronellal Schiff base 67801-36-9 DEFHJ 247 4,4a,5,9b-tetrahydroindeno[1,2- 18096-62-3 BCEFGJK d][1,3]dioxine 249 Hydroxy-citronellol 107-74-4 CEFGIJK 252 2-cyclododecylpropan-1-ol 118562-73-5 DEFHJK 253 Hydrocitronitrile 54089-83-7 CEFHJK 254 Hydrocinnamyl alcohol 122-97-4 BCEFHIK 256 Hydratropaldehyde dimethyl acetal 90-87-9 ACEFHJK 259 5-ethyl-4-hydroxy-2-methylfuran- 27538-09-6 CFGIK 3(2H)-one 260 2,3-dihydro-3,3-dimethyl-1H-indene- 173445-44-8 DHJK 5-propanal 261 3-(3,3-dimethyl-2,3-dihydro-1H- 173445-65-3 DHJK inden-5-yl)propanal 263 Hexyl octanoate 1117-55-1 DEFHJK 267 Hexyl hexanoate 6378-65-0 DEFHJKL 269 Hexyl cinnamic aldehyde 101-86-0 DHJ 271 Hexyl benzoate 6789-88-4 DEFHJK 274 Hexenyl tiglate 84060-80-0 BDEFHJK 276 (E)-3,7-dimethylocta-2,6-dien-1-yl 3681-73-0 DEFHJ palmitate 277 Hexadecanolide 109-29-5 DEFGJK 278 2-butyl-4,4,6-trimethyl-1,3-dioxane 54546-26-8 ADEFHIJKL 280 Ethyl (1R,2R,3R,4R)-3- 116126-82-0 BDEFHIJK isopropylbicyclo[2.2.1]hept-5-ene-2- carboxylate 281 3a,4,5,6,7,7a-hexahydro-1H-4,7- 5413-60-5 CEFGJK methanoinden-6-yl acetate 285 2-(1-(3,3- 141773-73-1 DEFHJ dimethylcyclohexyl)ethoxy)-2- methylpropyl propionate 286 Heliotropine diethyl acetal 40527-42-2 CEFGJ 288 Helional 1205-17-0 CHJK 289 (E)-oxacyclohexadec-13-en-2-one 111879-80-2 DGJK 290 Gyrane 24237-00-1 ADEFHIJKL 292 Guaiol 489-86-1 DEFHJK 293 1-(2,6,6-trimethylcyclohex-2-en-1- 68611-23-4 DHJK yl)pentan-3-one 294 Ethyl 2-ethyl-6,6-dimethylcyclohex- 57934-97-1 BDEFHIJK 2-ene-1-carboxylate 295 Germacrene B 15423-57-1 DEFHJK 296 Germacrene D 23986-74-5 DEFHJK 300 Geranyl phenylacetate 102-22-7 DFHJ 301 Geranyl phenyl acetate 71648-43-6 DFHJ 303 Geranyl linalool 1113-21-9 DFHJ 307 Geranyl cyclopentanone 68133-79-9 DHJK 316 gamma-Undecalactone (racemic) 104-67-6 DEFHJKL 317 gamma-Terpinyl acetate 10235-63-9 BDHJK 318 gamma-Terpineol 586-81-2 BCGIJK 321 gamma-Nonalactone 104-61-0 BCEFHIKL 322 gamma-Muurolene 30021-74-0 DEFHJKL 323 gamma-(E)-6-(pent-3-en-1- 63095-33-0 BCEFHKL yl)tetrahydro-2H-pyran-2-one 324 gamma-Ionone 79-76-5 BDEFHIJK 325 gamma-Himachalene 53111-25-4 BDEFHJKL 328 gamma-Gurjunene 22567-17-5 DEFHJKL 329 gamma-Eudesmol 1209-71-8 DFHJK 330 gamma-Dodecalactone 2305-05-7 DEFHJK 331 gamma-Damascone 35087-49-1 BDEFHIJK 332 gamma-Decalactone 706-14-9 BDEFHIJKL 333 gamma-Cadinene 39029-41-9 DEFHJKL 334 1-(3,3-dimethylcyclohexyl)pent-4- 56973-87-6 BDEFHJK en-1-one 335 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJK hexahydrocyclopenta[g]isochromene 336 Furfuryl octanoate 39252-03-4 DEFHJK 338 Furfuryl hexanoate 39252-02-3 CEFHJK 339 Furfuryl heptanoate 39481-28-2 CEFHJK 342 2-methyldecanenitrile 69300-15-8 BDEFHJKL 343 8,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJK hexahydro-1H-4,7-methanoinden-6- yl propionate 344 Ethyl (3aR,4S,7R,7aR)-octahydro- 80657-64-3 DEFHIJK 3aH-4,7-methanoindene-3a- carboxylate 347 Diethyl cyclohexane-1,4- 72903-27-6 CEFHJK dicarboxylate 349 (6-isopropyl-9-methyl-1,4- 63187-91-7 CEFHJ dioxaspiro[4.5]decan-2-yl)methanol 350 2-isobutyl-4-methyltetrahydro-2H- 63500-71-0 BCEFHIJK pyran-4-ol 352 Undec-10-enenitrile 53179-04-7 BDEFHJK 353 (Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2 CEFGJK methanochromen-2-one 356 3-(2-ethylphenyl)-2,2- 67634-15-5 BDHJK dimethylpropanal 358 (E)-4,8-dimethyldeca-4,9-dienal 71077-31-1 BDFHJK 359 (E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK 1,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3- methylbutan-2-ol 360 8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3 DEFHJK hexahydro-1H-4,7-methanoinden-6- yl acetate 361 3-(4-ethylphenyl)-2,2- 134123-93-6 DEFHJK dimethylpropanenitrile 362 2-heptylcyclopentan-1-one 137-03-1 DFHJKL 363 1-ethoxyethoxy Cyclododecane 389083-83-4 DEFHJK 364 3-cyclohexene-1-carboxylic acid, 815580-59-7 ACHIJKL 2,6,6-trimethyl-, methyl ester 368 Farnesyl acetate 29548-30-9 DEFHJK 369 Farnesol 4602-84-0 DEFHJK 370 Oxacyclohexadecan-2-one 106-02-5 DEFGJK 371 1-cyclopentadec-4-en-1-one 14595-54-1 DEFGJK 372 1-cyclopentadec-4-en-1-one 35720-57-1 DEFGJK 373 2-methoxy-4-(4- 128489-04-3 CGJ methylenetetrahydro-2H-pyran-2- yl)phenol 374 Eugenyl acetate 93-28-7 CFHJK 375 Eugenol 97-53-0 CHIK 377 Ethylmethylphenylglycidate 77-83-8 CFHJK 378 Ethylene brassylate 105-95-3 DFGJ 381 Ethyl undecylenate 692-86-4 DEFHJK 385 Ethyl palmitate 628-97-7 DEFHJ 386 Ethyl nonanoate 123-29-5 BDEFHJKL 388 Ethyl myristate 124-06-1 DEFHJK 390 Ethyl linalool 10339-55-6 BCEFHJK 391 Ethyl laurate 106-33-2 DEFHJK 394 Ethyl hexyl ketone 925-78-0 ADFHIKL 397 Ethyl decanoate 110-38-3 BDEFHJK 398 Ethyl gamma-Safranate 35044-57-6 ADHIJK 407 Ethyl 3-phenylglycidate 121-39-1 CGJK 413 6-ethyl-2,10,10-trimethyl-1- 79893-63-3 BDEFHIJK oxaspiro[4.5]deca-3,6-diene 414 Elemol 639-99-6 DEFHJK 415 (2-(1-ethoxyethoxy)ethyl)benzene 2556-10-7 BCEFHJK 416 (E)-3-methyl-5-(2,2,3- 67801-20-1 DHJK trimethylcyclopent-3-en-1-yl)pent-4- en-2-ol 417 d-xylose 58-86-6 CGIJ 418 (E)-4-((3aS,7aS)-octahydro-5H-4,7- 30168-23-1 DFHJK methanoinden-5-ylidene)butanal 421 Dodecanal dimethyl acetal 14620-52-1 DEFHJK 424 d-Limonene 5989-27-5 ADEFGIJKL 425 Dipropylene Glycol 25265-71-8 CEFGIK 426 Dispirone 83863-64-3 BDEFHJK 428 Diphenyloxide 101-84-8 BDEFHK 429 Diphenylmethane 101-81-5 DEFGK 432 Dimethyl benzyl carbinyl butyrate 10094-34-5 DEFHJK 436 2,6-dimethyloct-7-en-4-one 1879-00-1 ADEFHIJKL 441 Octahydro-1H-4,7-methanoinden-5- 64001-15-6 DEFHJKL yl acetate 444 Dihydrocarveol acetate 20777-49-5 BDEFHIJK 445 Dihydrocarveol 619-01-2 BCEFHIJKL 449 Dihydro Linalool 18479-51-1 BCEFGIJKL 450 Dihydro Isojasmonate 37172-53-5 DHJK 453 Dibutyl sulfide 544-40-1 ADEFHIKL 457 Dibenzyl 103-29-7 DEFGJK 459 delta-Undecalactone 710-04-3 DEFHJKL 461 delta-Elemene 20307-84-0 BDEFHJK 462 delta-Guaiene 3691-11-0 DEFHJKL 463 delta-Dodecalactone 713-95-1 DEFHJK 464 delta-Decalactone 705-86-2 BDEFHIJKL 465 delta-Cadinene 483-76-1 DEFHJKL 466 delta-damascone 57378-68-4 ADHIJK 467 delta-Amorphene 189165-79-5 DEFHJKL 468 delta-3-Carene 13466-78-9 ADEFGIJKL 470 Decylenic alcohol 13019-22-2 BDEFHJK 471 Decyl propionate 5454-19-3 DEFHJK 473 Decanal diethyl acetal 34764-02-8 DEFHJK 474 Decahydro-beta-naphthol 825-51-4 BCEFGIK 475 1-cyclohexylethyl (E)-but-2-enoate 68039-69-0 BDFHJK 478 3-(4-isopropylphenyl)-2- 103-95-7 BDFHJK methylpropanal 479 Cyclotetradecane 295-17-0 DEFGJKL 480 Cyclopentadecanone 502-72-7 DEFGJK 482 Cyclohexyl salicylate 25485-88-5 DFGJ 484 3a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK methanoinden-6-yl butyrate 485 Cyclic ethylene dodecanedioate 54982-83-1 DFGJ 486 8,8-dimethyl-1,2,3,4,5,6,7,8- 68991-97-9 DHJK octahydronaphthalene-2- carbaldehyde 487 3a,4,5,6,7,7a-hexahydro-1H-4,7- 67634-20-2 DEFHJK methanoinden-5-yl isobutyrate 488 Curzerene 17910-09-7 DHJK 491 Cumic alcohol 536-60-7 CHIJK 493 Coumarone 1646-26-0 BCEFHIK 497 2-(3-phenylpropyl)pyridine 2110-18-1 CEFHJK 498 Dodecanenitrile 2437-25-4 DEFHJK 501 (E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ 502 Citryl acetate 6819-19-8 DFHJK 503 Citrus Propanol 15760-18-6 CEFHIJK 505 Citronitrile 93893-89-1 CEFHJK 519 Citral propylene glycol acetal 10444-50-5 CEFHJK 520 Citral dimethyl acetal 7549-37-3 BCEFHJK 521 Citral diethyl acetal 7492-66-2 BDEFHJK 524 cis-Ocimene 3338-55-4 ADGIKL 527 cis-Limonene oxide 13837-75-7 ADEFGIJKL 529 Cis-iso-ambrettolide 36508-31-3 DGJ 530 cis-6-nonenol 35854-86-5 BCEFHIKL 531 cis-carveol 1197-06-4 BCHIJK 532 cis-4-Decen-1-al 21662-09-9 ADHKL 534 cis-3-hexenyl-cis-3-hexenoate 61444-38-0 BDEFHJK 537 cis-3-Hexenyl salicylate 65405-77-8 DEFGJ 541 Cis-3-hexenyl Benzoate 25152-85-6 DEFHJK 544 cis-3-Hexenyl 2-methylbutyrate 53398-85-9 ADEFHJKL 546 cis-3, cis-6-nonadienol 53046-97-2 ACEFHK 548 Cinnamyl propionate 103-56-0 DEFHJK 550 Cinnamyl isobutyrate 103-59-3 DEFHJK 551 Cinnamyl formate 104-65-4 BCEFHK 552 Cinnamyl cinnamate 122-69-0 DHJ 553 Cinnamyl acetate 103-54-8 BCEFHK 555 Cinnamic alcohol 104-54-1 BCEFHIK 558 Cetyl alcohol 36653-82-4 DEFHJ 559 (E)-1-(2,6,6-trimethylcyclohex-2-en- 79-78-7 DHJK 1-yl)hepta-1,6-dien-3-one 560 2-methyl-4-(2,6,6-trimethylcyclohex- 65405-84-7 DFHJK 1-en-1-yl)butanal 561 (3aR,5aR,9aR,9bR)-3a,6,6,9a- 3738-00-9 DEFHJK tetramethyldodecahydronaphtho[2,1- b]furan 562 1,6-dioxacycloheptadecan-7-one 6707-60-4 DGJ 563 1-(6-(tert-butyl)-1,1-dimethyl-2,3- 13171-00-1 DEFHJK dihydro-1H-inden-4-yl)ethan-1-one 565 Cedryl methyl ether 19870-74-7 ADEFHJK 566 Cedryl formate 39900-38-4 BDEFHJK 567 Cedryl acetate 77-54-3 DEFHJK 568 (4Z,8Z)-1,5,9-trimethyl-13- 71735-79-0 DFHJK oxabicyclo[10.1.0]trideca-4,8-diene 569 Cedrol 77-53-2 DEFHJK 570 5-methyl-1-(2,2,3- 139539-66-5 DEFHJK trimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 571 5-methyl-1-(2,2,3- 426218-78-2 DFHJ trimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 572 1,1,2,3,3-pentamethyl-1,2,3,5,6,7- 33704-61-9 BDEFHIJK hexahydro-4H-inden-4-one 573 Caryophyllene alcohol acetate 32214-91-8 DEFHJK 574 Caryolan-1-ol 472-97-9 DEFHJK 577 Carvyl acetate 97-42-7 BDHIJK 578 Caprylnitrile 124-12-9 ACEFGIKL 580 Caprylic alcohol 111-87-5 ACEFGIKL 581 Caprylic acid 124-07-2 BCEFHIK 582 Capric acid 334-48-5 DEFHJK 584 Capraldehyde 112-31-2 ADHKL 586 3-(4-methoxyphenyl)-2- 5462-06-6 BCHJK methylpropanal 587 Camphorquinone 10373-78-1 ACEFGIJK 589 Camphene 79-92-5 ADEFGIJKL 591 Ethyl 2-methyl-4-oxo-6- 59151-19-8 DHJ pentylcyclohex-2-ene-1-carboxylate 592 Butylated hydroxytoluene 128-37-0 DEFGIJK 594 Butyl stearate 123-95-5 DEFHJ 595 Butyl butyryl lactate 7492-70-8 CEFGJK 599 Butyl 10-undecenoate 109-42-2 DEFHJK 600 2-methyl-4-(2,2,3- 72089-08-8 DEFHJK trimethylcyclopent-3-en-1-yl)butan- 1-ol 601 3-(4-(tert-butyl)phenyl)propanal 18127-01-0 BDHJK 603 Bornyl isobutyrate 24717-86-0 BDEFHIJK 604 Bornyl acetate 76-49-3 ADEFHIJKL 606 2-ethoxy-2,6,6-trimethyl-9- 68845-00-1 BDEFHJK methylenebicyclo[3.3.1]nonane 607 (ethoxymethoxy)cyclododecane 58567-11-6 DEFHJK 608 Bisabolene 495-62-5 DEFHJK 609 Bigarade oxide 72429-08-4 ADEFHJKL 610 beta-Vetivone 18444-79-6 DHJK 611 beta-Terpinyl acetate 10198-23-9 BDHJK 612 beta-Terpineol 138-87-4 BCGIJK 613 beta-Sinensal 60066-88-8 DHJK 614 beta-Sesquiphellandrene 20307-83-9 DEFHJK 615 beta-Selinene 17066-67-0 BDEFGJK 616 beta-Santalol 77-42-9 DEFHJK 618 beta-Pinene 127-91-3 ADEFGIJKL 620 beta-Naphthyl ethyl ether 93-18-5 BDEFHJK 621 beta-Patchoulline 514-51-2 BDEFGJKL 624 beta-Himachalene Oxide 57819-73-5 BDFHJK 625 beta-Himachalene 1461-03-6 DEFHJKL 626 beta-Guaiene 88-84-6 DEFHJKL 627 (2,2-dimethoxyethyl)benzene 101-48-4 DHJK 628 beta-Farnesene 18794-84-8 DEFHJK 631 beta-Copaene 18252-44-3 BDEFHJKL 632 beta-Cedrene 546-28-1 BDEFGJKL 633 beta-Caryophyllene 87-44-5 DEFHJKL 635 beta-Bisabolol 15352-77-9 DFHJK 636 Beta ionone epoxide 23267-57-4 BDEFHIJK 638 Bergaptene 484-20-8 CGJ 639 Benzyl-tert-butanol 103-05-9 CEFGJK 644 Benzyl laurate 140-25-0 DEFHJ 649 Benzyl dimethyl carbinol 100-86-7 BCEFGIK 650 Benzyl cinnamate 103-41-3 DHJ 653 Benzyl benzoate 120-51-4 DHJ 655 Benzophenone 119-61-9 DEFHK 658 7-isopentyl-2H- 362467-67-2 DHJ benzo[b][1,4]dioxepin-3(4H)-one 659 2′-isopropyl-1,7,7- 188199-50-0 DEFHJK trimethylspiro[bicyclo[2.2.1]heptane- 2,4′-[1,3]dioxane] 660 4-(4-methylpent-3-en-1-yl)cyclohex- 21690-43-7 DEFHJK 3-ene-1-carbonitrile 661 Aurantiol 89-43-0 DEFHJ 663 Anisyl phenylacetate 102-17-0 DFHJ 668 Methyl (E)-octa-4,7-dienoate 189440-77-5 ACEFHKL 671 Amyl Cinnamate 3487-99-8 DEFHJK 673 (3aR,5aS,9aS,9bR)-3a,6,6,9a- 6790-58-5 DEFHJK tetramethyldodecahydronaphtho[2,1- b]furan 674 (4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6 DEFHJK hexamethyloctahydro-4H-4a,9- methanoazuleno[5,6-d][1,3]dioxole 675 2,5,5-trimethyl-1,2,3,4,5,6,7,8- 71832-76-3 DEFHJK octahydronaphthalen-2-ol 676 2,5,5-trimethyl-1,2,3,4,5,6,7,8- 41199-19-3 DEFHJK octahydronaphthalen-2-ol 677 1-((2-(tert- 139504-68-0 DEFHJK butyl)cyclohexyl)oxy)butan-2-ol 678 (3S,5aR,7aS,11aS,11bR)-3,8,8,11a- 57345-19-4 DEFHJ tetramethyldodecahydro-5H-3,5a- epoxynaphtho[2,1-c]oxepine 679 2,2,6,6,7,8,8-heptamethyldecahydro- 476332-65-7 ADEFHJK 2H-indeno[4,5-b]furan 680 2,2,6,6,7,8,8-heptamethyldecahydro- 647828-16-8 ADEFHJK 2H-indeno[4,5-b]furan 681 Amber acetate 37172-02-4 BDEFHJK 682 Alpinofix 811436-82-5 DEFHJ 683 alpha-Thujone 546-80-5 ADEFGIJKL 684 alpha-Vetivone 15764-04-2 DHJK 686 alpha-Terpinyl propionate 80-27-3 BDEFHJK 691 alpha-Sinensal 17909-77-2 DHJK 692 alpha-Selinene 473-13-2 BDEFHJK 693 alpha-Santalene 512-61-8 ADEFHJKL 694 alpha-Santalol 115-71-9 DEFHJK 696 alpha-Patchoulene 560-32-7 ADEFHJKL 697 alpha-neobutenone 56973-85-4 BDHJK 698 alpha-Muurolene 10208-80-7 DEFHJKL 700 alpha-methyl ionone 127-42-4 BDHJK 702 alpha-Limonene 138-86-3 ADEFGIJKL 704 alpha-Irone 79-69-6 BDHJK 706 alpha-Humulene 6753-98-6 DEFHJK 707 alpha-Himachalene 186538-22-7 BDEFHJK 708 alpha-Gurjunene 489-40-7 BDEFHJKL 709 alpha-Guaiene 3691-12-1 DEFHJKL 710 alpha-Farnesene 502-61-4 DEFHJK 711 alpha-Fenchene 471-84-1 ADEFGIJKL 712 alpha-Eudesmol 473-16-5 DEFHJK 713 alpha-Curcumene 4176-17-4 DEFHJK 714 alpha-Cubebene 17699-14-8 ADEFHJKL 715 alpha-Cedrene epoxide 13567-39-0 ADEFHJK 716 alpha-Cadinol 481-34-5 DEFHJK 717 alpha-Cadinene 24406-05-1 DEFHJKL 718 alpha-Bisabolol 515-69-5 DFHJK 719 alpha-bisabolene 17627-44-0 DEFHJK 720 alpha-Bergamotene 17699-05-7 BDEFHJKL 721 alpha-Amylcinnamyl alcohol 101-85-9 DEFHJ 722 alpha-Amylcinnamyl acetate 7493-78-9 DEFHJ 723 alpha-Amylcinnamaldehyde diethyl 60763-41-9 DEFHJ acetal 724 alpha-Amylcinnamaldehyde 122-40-7 DHJK 725 alpha-Amorphene 23515-88-0 DEFHJKL 726 alpha-Agarofuran 5956-12-7 BDEFHJK 727 1-methyl-4-(4-methyl-3-penten-1- 52475-86-2 DFHJK yl)-3-Cyclohexene-1-carboxaldehyde 730 1-Phenyl-2-pentanol 705-73-7 CEFHK 731 1-Phenyl-3-methyl-3-pentanol 10415-87-9 CEFHJK 733 2,3,4-trimethoxy-benzaldehyde 2103-57-3 BCGI 735 2,4,5-trimethoxy-benzaldehyde 4460-86-0 BCG 736 2,4,6-trimethoxybenzaldehyde 830-79-5 BCGI 738 2,4-Nonadienal 6750-03-4 ACHKL 741 2,6,10-Trimethylundecanal 105-88-4 BDFGJK 742 alpha,4-Dimethyl benzenepropanal 41496-43-9 ACHJK 746 Allyl cyclohexyl propionate 2705-87-5 BDEFHJK 748 Allyl amyl glycolate 67634-00-8 BCEFGJK 750 Allo-aromadendrene 25246-27-9 BDEFHJKL 752 Aldehyde C-11 143-14-6 ADHJK 754 Methyl (E)-2-(((3,5- 94022-83-0 DEFHJ dimethylcyclohex-3-en-1- yl)methylene)amino)benzoate 757 2,6,10-trimethylundec-9-enal 141-13-9 BDFHJK 758 Acetoxymethyl-isolongifolene 59056-62-1 BDEFHJK (isomers) 763 Acetate C9 143-13-5 BDEFHJKL 764 Acetarolle 744266-61-3 DFHJK 766 Acetaldehyde phenylethyl propyl 7493-57-4 CEFHJK acetal 767 Acetaldehyde dipropyl acetal 105-82-8 ACEFGIKL 768 Acetaldehyde benzyl 2-methoxyethyl 7492-39-9 BCEFHJK acetal 769 (Z)-2-(4-methylbenzylidene)heptanal 84697-09-6 DHJ 770 9-decenal 39770-05-3 ADHKL 771 8-Hexadecenolide 123-69-3 DGJ 772 7-Methoxycoumarin 531-59-9 CHK 774 7-epi-alpha-Selinene 123123-37-5 BDEFHJK 775 7-eip-alpha-Eudesmol 123123-38-6 DEFHJK 776 7-Acetyl-1,1,3,4,4,6- 1506-02-1 DEFHJ hexamethyltetralin 778 6-Isopropylquinoline 135-79-5 CEFHJK 781 6,6-dimethyl-2-norpinene-2- 33885-51-7 BCFHJK propionaldehyde 782 6,10,14-trimethyl-2-Pentadecanone 502-69-2 DEFHJK 786 5-Isopropenyl-2-methyl-2- 13679-86-2 ACGIJKL vinyltetrahydrofuran 788 5-Cyclohexadecenone 37609-25-9 DEFGJK 791 4-Terpinenol 562-74-3 BCHIJK 792 4-Pentenophenone 3240-29-7 BCEFHIK 800 4-Carvomenthenol 28219-82-1 BCHIJK 802 4,5,6,7-Tetrahydro-3,6- 494-90-6 BCEFHIJKL dimethylbenzofuran 803 4-(p-Methoxyphenyl)-2-butanone 104-20-1 BCEFHJK 804 3-Thujopsanone 25966-79-4 BDEFHJK 805 3-Propylidenephthalide 17369-59-4 CEFHK 806 3-Nonylacrolein 20407-84-5 BDFHJK 807 3-Methyl-5-phenyl-1-pentanal 55066-49-4 BDFHJK 814 3-Hexenyl isovalerate 10032-11-8 ADEFHJKL 821 3,6-Dimethyl-3-octanyl acetate 60763-42-0 ADEFHIJKL 824 3,4,5-trimethoxybenzaldehyde 86-81-7 BCGIK 826 3-(p- 7775-00-0 BDFHJK Isopropylphenyl)propionaldehyde 827 2-Undecenenitrile 22629-48-7 BDEFHJK 828 2-Undecenal 2463-77-6 ADHJK 829 2-trans-6-trans-Nonadienal 17587-33-6 ACHKL 831 2-Phenylethyl butyrate 103-52-6 DEFHJK 833 2-Phenyl-3-(2-furyl)prop-2-enal 57568-60-2 CHJ 834 2-Phenoxyethanol 122-99-6 BCEFGIK 837 2-Nonen-1-al 2463-53-8 ADHKL 839 2-Nonanol 628-99-9 BDEFGIKL 840 2-Nonanone 821-55-6 ADFHIKL 849 2-Isobutyl quinoline 93-19-6 CEFHJK 850 2-Hexylidene cyclopentanone 17373-89-6 DFHJKL 852 2-Heptyl tetrahydrofuran 2435-16-7 BDEFHJKL 856 2-Decenal 3913-71-1 ADHKL 864 2,6-Nonadienal 26370-28-5 ACHKL 865 2,6-Nonadien-1-ol 7786-44-9 ACEFHK 866 2,6-dimethyl-octanal 7779-07-9 ADFGIJKL 868 1-Decanol 112-30-1 BDEFGJK 869 1-Hepten-1-ol, 1-acetate 35468-97-4 ACEFHKL 870 10-Undecen-1-ol 112-43-6 DEFHJK 871 10-Undecenal 112-45-8 ADHJK 872 10-epi-gamma-Eudesmol 15051-81-7 DFHJK 873 1,8-Thiocineol 68391-28-6 ADEFHIJKL 876 1,3,5-undecatriene 16356-11-9 ADEFHJKL 877 1,2-Dihydrolinalool 2270-57-7 BCEFGIJKL 878 1,3,3-trimethyl-2-norbornanyl 13851-11-1 ADEFHIJKL acetate 879 1,1,2,3,3-Pentamethylindan 1203-17-4 ADHIJKL 881 (Z)-6,10-dimethylundeca-5,9-dien-2- 3239-37-0 DEFHJK yl acetate 884 (Z)-3-Dodecenal 68141-15-1 BCFHJK 885 (S)-gamma-Undecalactone 74568-05-1 DEFHJKL 886 (R)-gamma-Undecalactone 74568-06-2 DEFHJKL 890 (E)-6,10-dimethylundeca-5,9-dien-2- 3239-35-8 DEFHJK yl acetate 892 (2Z)-3-methyl-5-phenyl-2- 53243-59-7 DEFHJK Pentenenitrile 893 (2S,5S,6S)-2,6,10,10-tetramethyl-1- 65620-50-0 DFHIJK oxaspiro[4_5]decan-6-ol 894 (2E)-3-methyl-5-phenyl-2- 53243-60-0 CEFHJK pentenenitrile 897 (+)-Dihydrocarveol 22567-21-1 BCEFHIJKL 905 Menthone 89-80-5 ADEFGIJKL 908 (R,E)-2-methyl-4-(2,2,3- 185068-69-3 CHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 912 2-(8-isopropyl-6- 68901-32-6 DEFHJK methylbicyclo[2.2.2]oct-5-en-2-yl)- 1,3-dioxolane 913 gamma-methyl ionone 7388-22-9 BDHIJK 914 3-(3-isopropylphenyl)butanal 125109-85-5 BDHJK 916 3-(1-ethoxyethoxy)-3,7- 40910-49-4 BDEFHJK dimethylocta-1,6-diene 919 3a,4,5,6,7,7a-hexahydro-1H-4,7- 17511-60-3 CEFHJK methanoinden-6-yl propionate 920 Bulnesol 22451-73-6 DEFHJK 922 Benzyl phenylacetate 102-16-9 DHJ 923 Benzoin 119-53-9 CEFHJ 924 (E)-1,2,4-trimethoxy-5-(prop-1-en-1- 2883-98-9 BCFGJK yl)benzene 925 alpha,alpha,6,6-tetramethyl 33885-52-8 BDFHJK bicyclo[3.1.1]hept-2-ene-propanal 926 7-epi-sesquithujene 159407-35-9 DEFHJKL 927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJK hexamethylindan 928 3-Methylphenethyl alcohol 1875-89-4 BCEFHIK 929 3,6-Nonadien-1-ol 76649-25-7 ACEFHK 930 2-Tridecenal 7774-82-5 BDFHJK 933 Patchouli alcohol 5986-55-0 DEFHIJK 937 p-Cresyl isobutyrate 103-93-5 BDHJK 939 p-Cresyl n-hexanoate 68141-11-7 DEFHJK 941 5-hexyl-4-methyldihydrofuran- 67663-01-8 BDEFHIJKL 2(3H)-one 942 Ethyl (2Z,4E)-deca-2,4-dienoate 3025-30-7 BDEFHJK 943 Pelargene 68039-40-7 DEFHJK 945 2-cyclohexylidene-2- 10461-98-0 DFHJK phenylacetonitrile 946 Perillaldehyde 2111-75-3 ACHIJK 947 Perillyl acetate 15111-96-3 DFHJK 948 Perillyl alcohol 536-59-4 CHIJK 950 (2-isopropoxyethyl)benzene 68039-47-4 ACEFHJKL 951 Ethyl (2Z,4E)-deca-2,4-dienoate 313973-37-4 BDEFHJK 953 (2-(cyclohexyloxy)ethyl)benzene 80858-47-5 DEFHJK 954 Phenethyl 2-methylbutyrate 24817-51-4 DEFHJK 955 Phenethyl alcohol 60-12-8 BCEFGIK 959 Phenethyl phenylacetate 102-20-5 DHJ 962 Phenoxanol 55066-48-3 DEFHJK 965 Phenyl benzoate 93-99-2 DFHJK 967 Phenyl ethyl benzoate 94-47-3 DHJ 969 Phenylacetaldehyde ethyleneglycol 101-49-5 BCEFGIK acetal 973 2-(6,6-dimethylbicyclo[3.1.1]hept-2- 30897-75-7 ACFHIJKL en-2-yl)acetaldehyde 974 Pinocarveol 5947-36-4 BCEFGIJKL 976 Piperonyl acetone 55418-52-5 CEFGJ 978 3a,4,5,6,7,7a-hexahydro-1H-4,7- 68039-44-1 DEFHJK methanoinden-6-yl pivalate 980 (4aR,8aS)-7-methyloctahydro-1,4- 41724-19-0 CEFGJKL methanonaphthalen-6(2H)-one 982 p-Menth-3-en-1-ol 586-82-3 BCGIJK 985 (E)-3,3-dimethyl-5-(2,2,3- 107898-54-4 DHJK trimethylcyclopent-3-en-1-yl)pent-4- en-2-ol 988 1-methyl-4-(4-methylpent-3-en-1- 52474-60-9 DFHJK yl)cyclohex-3-ene-1-carbaldehyde 993 Propylene glycol 57-55-6 ACEFGIKL 998 p-Tolyl phenylacetate 101-94-0 DFHJ 1000 Ethyl 2,4,7-decatrienoate 78417-28-4 BDEFHJK 1003 2-benzyl-4,4,6-trimethyl-1,3-dioxane 67633-94-7 DEFHJK 1006 2,4-dimethyl-4- 82461-14-1 BDEFHJK phenyltetrahydrofuran 1007 (2R,4a′R,8a′R)-3,7′-dimethyl- 41816-03-9 DEFHJK 3′,4′,4a′,5′,8′,8a′-hexahydro-1′H- spiro[oxirane-2,2′- [1,4]methanonaphthalene] 1008 (Z)-6-ethylideneoctahydro-2H-5,8- 93939-86-7 BCEFHJKL methanochromene 1009 2-((S)-1-((S)-3,3- 236391-76-7 DFHJ dimethylcyclohexyl)ethoxy)-2- oxoethyl propionate 1010 Methyl 2,2-dimethyl-6- 81752-87-6 ADHIJKL methylenecyclohexane-1-carboxylate 1012 2-methyl-5-phenylpentan-1-ol 25634-93-9 DEFHJK 1016 4-methyl-2-phenyl-3,6-dihydro-2H- 60335-71-9 BCEFGJK pyran 1020 Sabinol 471-16-9 BCEFHIJKL 1021 Safrole 94-59-7 BCEFHK 1022 2,2,7,9-tetramethylspiro(5.5)undec- 502847-01-0 DHIJK 8-en-1-one 1023 3-methyl-5-(2,2,3- 65113-99-7 DEFHJK trimethylcyclopent-3-en-1-yl)pentan- 2-ol 1024 (Z)-2-ethyl-4-(2,2,3- 28219-61-6 DEFHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1025 (E)-2-methyl-4-(2,2,3- 28219-60-5 CHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1026 5-methoxyoctahydro-1H-4,7- 86803-90-9 CHJK methanoindene-2-carbaldehyde 1027 5-methoxyoctahydro-1H-4,7- 193425-86-4 CHJK methanoindene-2-carbaldehyde 1028 Sclareol 515-03-7 DEFHJ 1029 Sclareol oxide 5153-92-4 DEFHJK 1031 Selina-3,7(11)-diene 6813-21-4 DEFHJKL 1032 2-(1-(3,3- 477218-42-1 DEFHJ dimethylcyclohexyl)ethoxy)-2- methylpropyl cyclopropanecarboxylate 1033 3-(4-isobutylphenyl)-2- 6658-48-6 DHJK methylpropanal 1035 Spathulenol 6750-60-3 DEFHJK 1036 Spirambrene 533925-08-5 BCEFHJK 1037 Spirodecane 6413-26-9 BCEFGIJKL 1038 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3 DGJK 1-one 1042 2-(4-methylthiazol-5-yl)ethan-1-ol 137-00-8 CGIKL 1043 2-(heptan-3-yl)-1,3-dioxolane 4359-47-1 ACEFHIJKL 1045 (Z)-dodec-4-enal 21944-98-9 BDFHJK 1046 tau-Cadinol 5937-11-1 DEFHJK 1047 tau-Muurolol 19912-62-0 DEFHJK 1053 Tetrahydrojasmone 13074-63-0 BDFHIJKL 1057 2,6,10,10-tetramethyl-1- 36431-72-8 BDFHIJKL oxaspiro[4.5]dec-6-ene 1059 Thiomenthone 38462-22-5 BDEFHIJKL 1060 Thujopsene 470-40-6 BDEFGJKL 1062 Thymol methyl ether 1076-56-8 ADHIJKL 1063 1-(2,2,6-trimethylcyclohexyl)hexan- 70788-30-6 DEFHJK 3-ol 1064 trans, trans-2,4-Nonadienal 5910-87-2 ACHKL 1065 trans, trans-Farnesol 106-28-5 DEFHJK 1066 trans-2, cis-6-Nonadienal 557-48-2 ACHKL 1067 trans-2-Decenal 3913-81-3 ADHKL 1070 trans-2-Nonen-1-al 18829-56-6 ADHKL 1072 trans-3, cis-6-nonadienol 56805-23-3 ACEFHK 1073 trans-4-Decen-1-al 65405-70-1 ADHKL 1075 trans-ambrettolide 51155-12-5 DGJ 1077 trans-beta-ocimene 13877-91-3 ADGIKL 1078 trans-beta-Ocimene 3779-61-1 ADGIKL 1082 trans-Geraniol 106-24-1 BCHIK 1083 trans-Hedione 2570-03-8 DFHJK 1085 7-(1,1-Dimethylethyl)-2H-1,5- 195251-91-3 CEFHJ benzodioxepin-3(4H)-one 1089 Tricyclone 68433-81-8 DEFHJK 1090 Tridecyl alcohol 112-70-9 DEFGJK 1091 Triethyl citrate 77-93-0 CEFGJ 1093 Methyl 2-((1-hydroxy-3- 144761-91-1 DFHJ phenylbutyl)amino)benzoate 1095 1-((2E,5Z,9Z)-2,6,10- 28371-99-5 DHJK trimethylcyclododeca-2,5,9-trien-1- yl)ethan-1-one 1097 Decahydro-2,6,6,7,8,8-hexamethyl- 338735-71-0 BDEFHJK 2h-indeno(4,5-b)furan 1099 13-methyl oxacyclopentadec-10-en- 365411-50-3 DEFHJK 2-one 1102 Undecanal 112-44-7 BDHJK 1104 (E)-4-methyldec-3-en-5-ol 81782-77-6 BDEFHIJK 1105 Valencene 4630-07-3 BDEFHJK 1107 Valerianol 20489-45-6 DEFHJK 1111 Vanillin isobutyrate 20665-85-4 CHJ 1113 Vaniwhite 5533-03-9 CGIK 1116 (Z)-2-methyl-4-(2,6,6- 68555-62-4 BDFHJK trimethylcyclohex-2-en-1-yl)but-2- enal 1117 Methyl 2,4-dihydroxy-3,6- 4707-47-5 CGIJ dimethylbenzoate 1120 1-methoxy-3a,4,5,6,7,7a-hexahydro- 27135-90-6 ACEFHJKL 1H-4,7-methanoindene 1121 Methyl (Z)-2-((3-(4-(tert- 91-51-0 DFHJ butyl)phenyl)-2- methylpropylidene)amino)benzoate 1125 (Z)-hex-3-en-1-yl isobutyrate 41519-23-7 ADEFHJKL 1126 Vertacetal 5182-36-5 BCFHJK 1129 1-((3R,3aR,7R,8aS)-3,6,8,8- 32388-55-9 DHJK tetramethyl-2,3,4,7,8,8a-hexahydro- 1H-3a,7-methanoazulen-5-yl)ethan- 1-one 1131 Methyl (Z)-2-(((2,4- 68738-99-8 DEFHJ dimethylcyclohex-3-en-1- yl)methylene)amino)benzoate 1135 Vetiverol 89-88-3 CEFHIJK 1136 Vetivert Acetate 117-98-6 DEFHJK 1137 Decahydro-3H-spiro[furan-2,5′- 68480-11-5 DEFGJKL [4,7]methanoindene] 1138 (2Z,6E)-nona-2,6-dienenitrile 67019-89-0 ACEFHKL 1139 (Z)-cyclooct-4-en-1-yl methyl 87731-18-8 BCHJKL carbonate 1140 (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3 DEFHJK tetramethyldecahydro-1H- cyclopropa[e]azulen-4-ol 1142 3,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJ tetrahydronaphthalene-2-carbonitrile 1143 (1S,2S,3S,5R)-2,6,6- 133636-82-5 DEFHJK trimethylspiro[bicyclo[3.1.1]heptane- 3,1′-cyclohexan]-2′-en-4′-one 1144 1′,1′,5′,5′-tetramethylhexahydro- 154171-76-3 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′- [2,4a]methanonaphthalene] 1145 1′,1′,5′,5′-tetramethylhexahydro- 154171-77-4 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′- [2,4a]methanonaphthalene] K 1146 4-(4-hydroxy-3- 122-48-5 CEFGJ methoxyphenyl)butan-2-one 1147 (1R,8aR)-4-isopropyl-1,6-dimethyl- 41929-05-9 DEFHJKL 1,2,3,7,8,8a-hexahydronaphthalene

TABLE 2 List of materials with at least one MORV greater than 5 to 10 Number Material Name CAS Number Comment Code 2 2,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4 DFHJ 5,6,7,8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane 23 3a,5,6,7,8,8b-hexahydro- 823178-41-2 DEFHJK 2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-1,3-dioxole 141 2,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJK tetrahydroindeno[1,2-d][1,3]dioxine 185 (1-methyl-2-((1,2,2- 198404-98-7 DEFHJK trimethylbicyclo[3.1.0]hexan-3- yl)methyl)cyclopropyl)methanol 227 Isobornylcyclohexanol 68877-29-2 DEFHJK 230 Isobornyl cyclohexanol 66072-32-0 DEFHJK 246 Indol/Hydroxycitronellal Schiff base 67801-36-9 DEFHJ 248 Hydroxymethyl isolongifolene 59056-64-3 DEFHJK 343 8,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJK hexahydro-1H-4,7-methanoinden-6- yl propionate 359 (E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK 1,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3- methylbutan-2-ol 565 Cedryl methyl ether 19870-74-7 BDEFHJK 631 beta-Copaene 18252-44-3 BDEFHJKL 659 2′-isopropyl-1,7,7- 869292-93-3 BDEFHJK trimethylspiro[bicyclo[2.2.1]heptane- 2,4′-[1,3]dioxane] 674 (4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6 DEFHJK hexamethyloctahydro-4H-4a,9- methanoazuleno[5,6-d][1,3]dioxole 678 (3S,5aR,7aS,11aS,11bR)-3,8,8,11a- 57345-19-4 DEFHJ tetramethyldodecahydro-5H-3,5a- epoxynaphtho[2,1-c]oxepine 679 2,2,6,6,7,8,8-heptamethyldecahydro- 476332-65-7 DEFHJK 2H-indeno[4,5-b]furan 715 alpha-Cedrene epoxide 13567-39-0 BDEFHJK 758 Acetoxymethyl-isolongifolene 59056-62-1 DEFHJK (isomers) 1028 Sclareol 515-03-7 DEFHJ 1097 Decahydro-2,6,6,7,8,8-hexamethyl- 338735-71-0 DEFHJK 2h-indeno(4,5-b)furan

TABLE 3 List of materials with at least one MORV from 0.5 to less than 1 Number Material Name CAS Number Comment Code 12 1-ethoxy-4-(tert- 181258-89-9 ADEFHJK pentyl)cyclohexane 19 (3Z)-1-(2-buten-1-yloxy)-3- 888744-18-1 ADEFHJKL hexene 20 4-(2-methoxypropan-2-yl)-1- 14576-08-0 ADHIJKL methylcyclohex-1-ene 24 O-Methyl linalool 60763-44-2 ADHIJKL 26 o-Methoxycinnamaldehyde 1504-74-1 ACHK 27 Octanal, 3,7-dimethyl- 25795-46-4 ADGIJKL 53 3,3-Dimethyl-5(2,2,3- 329925-33-9 CEFHJ Trimethyl-3-Cyclopenten- 1yl)-4-Penten-2-ol 54 n-Hexyl salicylate 6259-76-3 DEFHJ 55 n-Hexyl 2-butenoate 19089-92-0 ADEFHJKL 59 Neryl Formate 2142-94-1 BCEFHJK 72 Methyl-beta-ionone 127-43-5 DHJK 73 Myroxide 28977-57-3 ADGIJKL 81 (E)-3,7-dimethylocta-4,6- 18479-54-4 BCEFGIJK dien-3-ol 84 (Z)-hex-3-en-1-yl 188570-78-7 BCEFHIKL cyclopropanecarboxylate 96 Methyl phenyl carbinyl 120-45-6 BCHJK propionate 97 Methyl phenylacetate 101-41-7 ACEFHIKL 107 2-methyl-6- 91069-37-3 BCEFGIKL oxaspiro[4.5]decan-7-one 111 Methyl geraniate 2349-14-6 BCHJKL 115 2-ethoxy-4- 5595-79-9 CFGK (methoxymethyl)phenol 116 Methyl 40203-73-4 ACEFHIKL cyclopentylideneacetate 125 Methoxymelonal 62439-41-2 ACGIJK 133 ((1s,4s)-4- 13828-37-0 BDEFHIJK isopropylcyclohexyl)methanol 147 Linalyl propionate 144-39-8 BDFHJK 150 Linalyl formate 115-99-1 ACFHJK 151 Linalyl butyrate 78-36-4 BDEFHJK 154 Linalyl acetate 115-95-7 BDHJK 157 Linalool 78-70-6 BCEFGIJK 163 (Z)-hex-3-en-1-yl methyl 67633-96-9 ACEFGKL carbonate 166 Lepidine 491-35-0 BCEFHIKL 169 L-Carvone 6485-40-1 ACGIJKL 181 Khusinil 75490-39-0 DHJK 191 Isoraldeine 1335-46-2 BDHIJK 194 Isopropylvinylcarbinol 4798-45-2 ACGIKL 198 Isopropyl 2-methylbutyrate 66576-71-4 ACEFGIJKL 201 Isopentyrate 80118-06-5 ADEFGIJKL 204 Isononyl acetate 40379-24-6 BDEFHJKL 205 Isononanol 27458-94-2 BDEFGIKL 213 Isoeugenyl acetate 93-29-8 CFHJK 214 Isoeugenol 97-54-1 CEFHIK 232 Isoborneol 124-76-5 ACEFHIJKL 237 Isoamyl octanoate 2035-99-6 DEFHJK 239 Isoamyl isobutyrate 2050-01-3 ACEFGIJKL 255 Hydrocinnamic acid 501-52-0 CEFHIK 258 Hydratopic alcohol 1123-85-9 BCEFHIK 264 Hexyl propanoate 2445-76-3 ADEFHIKL 270 Hexyl butyrate 2639-63-6 BDEFHJKL 273 Hexyl 2-methylbutanoate 10032-15-2 BDEFHJKL 275 Hexyl 2-furoate 39251-86-0 DEFHJK 282 Heptyl alcohol 111-70-6 ACEFGIKL 283 Heptyl acetate 112-06-1 ADEFHKL 284 Heptaldehyde 111-71-7 ACHIKL 287 Heliotropin 120-57-0 BCGIK 302 Geranyl nitrile 5146-66-7 BCEFHKL 306 Geranyl formate 105-86-2 BCEFHJK 308 Geranyl caprylate 51532-26-4 DEFHJ 310 Geranyl benzoate 94-48-4 DFHJ 312 Geranial 141-27-5 ACHIKL 314 N,2-dimethyl-N- 84434-18-4 BCEFHJK phenylbutanamide 319 gamma-Terpinene 99-85-4 ADEFGIJKL 346 2-(sec-butyl)cyclohexan-1- 14765-30-1 ADFHIKL one 354 3-(2-ethylphenyl)-2,2- 67634-14-4 BDHJK dimethylpropanal 355 2-(tert-butyl)cyclohexyl ethyl 67801-64-3 BDFHJK carbonate 365 2-(tert-butyl)cyclohexyl ethyl 81925-81-7 ACFHIKL carbonate 366 Fenchyl alcohol 1632-73-1 ACGIJKL 376 Eucalyptol 470-82-6 ADEFGIJKL 379 Ethyl vanillin acetate 72207-94-4 CHJ 387 Ethyl octanoate 106-32-1 BDEFHJKL 400 Ethyl cinnamate 103-36-6 BCEFHK 412 Ethyl 2- 2511-00-4 BDFHIJKL (cyclohexyl)propionate 419 d-p-8(9)-Menthen-2-one 5524-05-0 ACGIJKL 420 4-methyl-2-phenyltetrahydro- 94201-73-7 BDEFHJK 2H-pyran 437 Dihydromyrcenol 18479-58-8 ADEFGIJK 438 Dihydrojasmone 1128-08-1 BCFHIJKL 439 Dihydroisophorone 873-94-9 ACEFGIJKL 440 Dihydroeugenol 2785-87-7 CEFHIJK 442 Dihydrocoumarin 119-84-6 BCGIKL 443 Dihydrocarvone 7764-50-3 ACGIJKL 447 Dihydro-alpha-terpinyl 80-25-1 BDEFHIJKL acetate 448 Dihydro-alpha-ionone 31499-72-6 BDHIJK 454 Dibenzyl ether 103-50-4 DEFHJK 455 Dibutyl o-phthalate 84-74-2 DEFHJ 469 2-pentylcyclopentan-1-one 4819-67-4 BDFHIKL 472 Decyl anthranilate 18189-07-6 DEFHJ 477 Methyl (1s,4s)-1,4- 23059-38-3 ADEFHIJKL dimethylcyclohexane-1- carboxylate 481 Cyclohexylethyl acetate 21722-83-8 BDEFHJKL 492 Creosol 93-51-6 BCHIK 495 Cosmene 460-01-5 ADEFGIKL 496 4-cyclohexyl-2-methylbutan- 83926-73-2 BDEFGIJK 2-ol 504 2-benzyl-2-methylbut-3- 97384-48-0 BDHJK enenitrile 509 Citronellyl nitrile 51566-62-2 BCEFGIKL 510 Citronellyl phenylacetate 139-70-8 DFHJ 512 Citronellyl formate 105-85-1 BCEFGJKL 515 Citronellyl benzoate 10482-77-6 DFHJ 517 Citronellol 106-22-9 BCHIJKL 518 Citronellal 106-23-0 ACHIJKL 522 Citral 5392-40-5 ACHIKL 525 cis-Pinane 6876-13-7 ADEFGIJKL 526 (Z)-3-methyl-2-(pent-2-en-1- 488-10-8 BCHIJKL yl)cyclopent-2-en-1-one 528 cis-iso-Eugenol 5912-86-7 CEFHIK 535 cis-3-Hexenyl valerate 35852-46-1 BDEFHJKL 536 cis-3-Hexenyl tiglate 67883-79-8 BDEFHJK 538 cis-3-Hexenyl propionate 33467-74-2 ACEFHIKL 540 cis-3-Hexenyl butyrate 16491-36-4 ADEFHJKL 542 cis-3-Hexen-1-ol 928-96-1 ACEFHIKL 547 cis-2-Hexenol 928-94-9 ACEFHIKL 549 Cinnamyl nitrile 4360-47-8 ACEFGIK 554 Cinnamic aldehyde 104-55-2 ACHIK 556 Cinnamyl nitrile 1885-38-7 ACEFGIK 557 Chloroxylenol 88-04-0 BCHIJK 575 Carvacrol 499-75-2 DHIJK 576 Carvone 99-49-0 ACGIJKL 579 Carbitol 111-90-0 BCEFGIK 583 Caproyl alcohol 111-27-3 ACEFGIKL 585 2-(2,2,3-trimethylcyclopent-3- 15373-31-6 ACGIJKL en-1-yl)acetonitrile 588 Camphor 76-22-2 ACEFGIJKL 602 (E)-2-methyl-4-(2,6,6- 3155-71-3 DHJK trimethylcyclohex-1-en-1- yl)but-2-enal 605 Borneol 507-70-0 ACEFHIJKL 617 beta-Pinene epoxide 6931-54-0 ACEFGIJKL 619 beta-Phellandrene 555-10-2 ADEFGIJKL 640 Benzylacetone 2550-26-7 ACEFGIK 641 Benzyl salicylate 118-58-1 DFGJ 645 Benzyl isovalerate 103-38-8 BDEFHJK 647 Benzyl isobutyrate 103-28-6 BCHJK 651 Benzyl butyrate 103-37-7 BCEFHJK 652 Benzyl alcohol 100-51-6 ACEFGIKL 662 1-(3,3- 25225-08-5 ADEFHIJKL dimethylcyclohexyl)ethyl formate 664 Anisyl acetate 104-21-2 BCEFGK 665 Anisyl formate 122-91-8 BCEFGK 667 Anethole 104-46-1 ACEFHK 672 Amyl benzoate 2049-96-9 DEFHJK 687 alpha-Terpinyl acetate 80-26-2 BDHJK 699 alpha-methyl- 10528-67-3 BDEFHIK cyclohexanepropanol 701 alpha-methyl cinnamaldehyde 101-39-3 ACHIK 703 alpha-Isomethylionone 127-51-5 BDHIJK 740 2,5-Dimethyl-4-methoxy- 4077-47-8 ACEFGIJKL 3(2H)-furanone 743 Allyl phenoxyacetate 7493-74-5 BCGK 744 Allyl Phenethyl ether 14289-65-7 ACEFHK 745 Allyl heptanoate 142-19-8 ADEFHJKL 755 N-ethyl-N-(m- 179911-08-1 CEFHJK tolyl)propionamide 760 3-hydroxybutan-2-one 513-86-0 ACEFGIKL 761 Acetoanisole 100-06-1 BCEFHIK 777 6-Methylquinoline 91-62-3 BCEFHIKL 779 6,8-Diethyl-2-nonanol 70214-77-6 BDEFGIJKL 784 5-Methyl-3-heptanone 541-85-5 ACFGIKL 789 4-Vinylphenol 2628-17-3 BCHIK 796 4-hydroxy-3-methoxy- 458-36-6 CH cinnamaldehyde 797 4-Ethylguaiacol 2785-89-9 CEFHIK 799 4-Damascol 4927-36-0 BDFHJK 808 3-methyl-4-phenylpyrazole 13788-84-6 CEFHK 810 3-Methyl-1,2- 765-70-8 ACEFGIKL cyclopentanedione 811 3-Methoxy-5-methylphenol 3209-13-0 BCHIK 812 3-Methoxy-3-Methyl Butanol 56539-66-3 ACGIKL 817 3-Hexenol 544-12-7 ACEFHIKL 819 3,7-dimethyl-2-methylene-6- 22418-66-2 ADFHIJK octenal 820 3,7-dimethyl-1-octanol 106-21-8 BDEFGIJKL 832 2-Phenylethyl acetate 103-45-7 BCEFHK 835 2-Phenethyl propionate 122-70-3 BCEFHJK 836 2-Pentylcyclopentan-1-ol 84560-00-9 DEFHIKL 838 2-nonanone propylene glycol 165191-91-3 BDEFHJK acetal 845 2-Methoxy-3-(1- 24168-70-5 BCEFGIK methylpropyl)pyrazine 846 2-isopropyl-N,2,3- 51115-67-4 ACEFGIJK trimethylbutyramide 847 2-Isopropyl-5-methyl-2- 35158-25-9 ADFGIJKL hexenal 848 2-Isopropyl-4-methylthiazole 15679-13-7 ACHIJKL 851 2-Hexen-1-ol 2305-21-7 ACEFHIKL 858 2-Butoxyethanol 111-76-2 ACEFGIKL 875 1,4-Cineole 470-67-7 ADGIJKL 880 1-(2,6,6-Trimethyl-2- 43052-87-5 BDHIJK cyclohexen-1-yl)-2-buten-1- one 882 (Z)-3-hepten-1-yl acetate 1576-78-9 ACEFHKL 883 (S)-(1R,5R)-4,6,6- 1196-01-6 ACEFGIJKL trimethylbicyclo[3.1.1]hept-3- en-2-one 888 (R)-(−)-Linalool 126-91-0 BCEFGIJK 889 (l)-Citronellal 5949-05-3 ACHIJKL 891 (d)-Citronellal 2385-77-5 ACHIJKL 899 (+)-Citronellol 1117-61-9 BCHIJKL 900 (−)-Citronellol 7540-51-4 BCHIJKL 901 (+)-alpha-Pinene 7785-70-8 ADEFGIJKL 902 (+)-Carvone 2244-16-8 ACGIJKL 903 (−)-alpha-Pinene 7785-26-4 ADEFGIJKL 904 Methyl 2-methylbutyrate 868-57-5 ACEFGIKL 909 Hexyl tiglate 16930-96-4 BDEFHJKL 918 Allyl 2- 68901-15-5 CHJK (cyclohexyloxy)acetate 921 1,5- 75147-23-8 CFHIJK dimethylbicyclo[3.2.1]octan- 8-one oxime 931 alpha-acetoxystyrene 2206-94-2 ACEFHIK 940 p-Cymene 99-87-6 ADGIJKL 956 Phenethyl formate 104-62-1 ACEFHK 958 Phenethyl isobutyrate 103-48-0 DHJK 960 Phenethyl tiglate 55719-85-2 DHJK 971 Phenylethyl methacrylate 3683-12-3 DHJK 977 p- 4395-92-0 BDFHK Isopropylphenylacetaldehyde 981 1,2-dimethyl-3-(prop-1-en-2- 72402-00-7 BCEFGIJKL yl)cyclopentan-1-ol 983 p-Methoxyphenylacetone 122-84-9 BCEFHK 986 (2Z,5Z)-5,6,7-trimethylocta- 358331-95-0 ADHIJKL 2,5-dien-4-one 987 p-Propyl anisole 104-45-0 ADEFHKL 994 p-t-butyl phenyl acetaldehyde 109347-45-7 BDHJK 995 p-tert-Amyl cyclohexanol 5349-51-9 BDEFHIJK 1001 Racemic alpha-Pinene 80-56-8 ADEFGIJKL 1002 4-(4-hydroxyphenyl)butan-2- 5471-51-2 CEFGIK one 1004 Rhodinol 141-25-3 BCHIJKL 1005 Ethyl (2,3,6- 93981-50-1 BDEFHJKL trimethylcyclohexyl)carbonate 1011 1-(3,3- 25225-10-9 ADHIJKL dimethylcyclohexyl)ethyl acetate 1017 S)-(+)-Linalool 126-90-9 BCEFGIJK 1018 Sabinene 3387-41-5 ADEFGIJKL 1019 Sabinene hydrate 546-79-2 ADEFGIJKL 1030 Propyl (S)-2-(tert- 319002-92-1 BDEFHJK pentyloxy)propanoate 1039 Spirolide 699-61-6 BCGIKL 1040 (Z)-5-methylheptan-3-one 22457-23-4 BCEFGIJKL oxime 1041 1-phenylethyl acetate 93-92-5 ACEFHIK 1051 Tetrahydrogeranial 5988-91-0 ADGIJKL 1052 Tetrahydroionol 4361-23-3 BDEFHIJK 1054 Tetrahydrolinalool 78-69-3 BDEFGIJKL 1055 Tetrahydrolinalyl acetate 20780-48-7 ADEFHJKL 1058 Ethyl (1R,6S)-2,2,6- 22471-55-2 ADEFHIJKL trimethylcyclohexane-1- carboxylate 1061 Thymol 89-83-8 BDHIJK 1069 trans-2-Hexenol 928-95-0 ACEFHIKL 1071 trans-2-tert- 5448-22-6 ACGIJKL Butylcyclohexanol 1074 trans-alpha-Damascone 24720-09-0 BDHIJK 1076 trans-Anethole 4180-23-8 ACEFHK 1079 trans-Cinnamic acid 140-10-3 CEFHK 1081 trans-Dihydrocarvone 5948-04-9 ACGIJKL 1084 trans-Isoeugenol 5932-68-3 CEFHIK 1088 Trichloromethyl phenyl 90-17-5 BDEFGJ carbinyl acetate 1098 2-mercapto-2-methylpentan- 258823-39-1 ACEFHIJKL 1-ol 1110 Vanillin acetate 881-68-5 CH 1112 Vanitrope 94-86-0 CEFHK 1115 2,2,5-trimethyl-5- 65443-14-3 BDFGIJKL pentylcyclopentan-1-one 1118 Veratraldehyde 120-14-9 BCGIK 1119 (1R,5R)-4,6,6- 18309-32-5 ACEFGIJKL trimethylbicyclo[3.1.1]hept-3- en-2-one 1122 Verdol 13491-79-7 ACGIJKL 1127 4-(tert-butyl)cyclohexyl 10411-92-4 BDEFHJK acetate 1128 4-(tert-butyl)cyclohexyl 32210-23-4 BDEFHJK acetate 1133 Vethymine 7193-87-5 CEFGK 1134 4-methyl-4-phenylpentan-2-yl 68083-58-9 BDFHJK acetate 1141 (Z)-1-((2- 292605-05-1 ADEFHKL methylallyl)oxy)hex-3-ene

TABLE 4 List of materials with ALL MORVs from 1 to 5 Num- CAS Comment ber Material Name Number Code 7 3-methoxy-7,7-dimethyl-10- 216970-21-7 BDEFHJK methylenebicyclo[4.3.1]decane 14 Oxyoctaline formate 65405-72-3 DFHJK 39 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJK octahydronaphthalen-1-ol 48 Nootkatone 4674-50-4 DHJK 183 Khusimol 16223-63-5 CEFHJK 199 Isopimpinellin 482-27-9 CFGJ 206 Iso3-methylcyclopentadecan-1-one 3100-36-5 DEFGJK 212 Isoeugenyl benzyl ether 120-11-6 DFHJ 215 1-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2 DHJK 1,2,3,4,5,6,7,8-octahydronaphthalen- 2-yl)ethan-1-one 229 Isobornyl isobutyrate 85586-67-0 BDEFHIJK 260 2,3-dihydro-3,3-dimethyl-1H-indene- 173445-44-8 DHJK 5-propanal 261 3-(3,3-dimethyl-2,3-dihydro-1H- 173445-65-3 DHJK inden-5-yl)propanal 281 3a,4,5,6,7,7a-hexahydro-1H-4,7- 5413-60-5 CEFGJK methanoinden-6-yl acetate 329 gamma-Eudesmol 1209-71-8 DFHJK 335 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJK hexahydrocyclopenta[g]isochromene 353 (Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2 CEFGJK methanochromen-2-one 360 8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3 DEFHJK hexahydro-1H-4,7-methanoinden-6- yl acetate 441 Octahydro-1H-4,7-methanoinden-5- 64001-15-6 DEFHJKL yl acetate 484 3a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK methanoinden-6-yl butyrate 487 3a,4,5,6,7,7a-hexahydro-1H-4,7- 67634-20-2 DEFHJK methanoinden-5-yl isobutyrate 488 Curzerene 17910-09-7 DHJK 501 (E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ 566 Cedryl formate 39900-38-4 BDEFHJK 567 Cedryl acetate 77-54-3 DEFHJK 569 Cedrol 77-53-2 DEFHJK 570 5-methyl-1-(2,2,3- 139539-66-5 DEFHJK trimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 573 Caryophyllene alcohol acetate 32214-91-8 DEFHJK 574 Caryolan-1-ol 472-97-9 DEFHJK 603 Bornyl isobutyrate 24717-86-0 BDEFHIJK 616 beta-Santalol 77-42-9 DEFHJK 621 beta-Patchoulline 514-51-2 BDEFGJKL 624 beta-Himachalene Oxide 57819-73-5 BDFHJK 627 (2,2-dimethoxyethyl)benzene 101-48-4 DHJK 632 beta-Cedrene 546-28-1 BDEFGJKL 663 Anisyl phenylacetate 102-17-0 DFHJ 680 2,2,6,6,7,8,8-heptamethyldecahydro- 647828-16-8 ADEFHJK 2H-indeno[4,5-b]furan 684 alpha-Vetivone 15764-04-2 DHJK 694 alpha-Santalol 115-71-9 DEFHJK 696 alpha-Patchoulene 560-32-7 ADEFHJKL 708 alpha-Gurjunene 489-40-7 BDEFHJKL 712 alpha-Eudesmol 473-16-5 DEFHJK 714 alpha-Cubebene 17699-14-8 ADEFHJKL 726 alpha-Agarofuran 5956-12-7 BDEFHJK 750 Allo-aromadendrene 25246-27-9 BDEFHJKL 764 Acetarolle 744266-61-3 DFHJK 775 7-eip-alpha-Eudesmol 123123-38-6 DEFHJK 776 7-Acetyl-1,1,3,4,4,6- 1506-02-1 DEFHJ hexamethyltetralin 788 5-Cyclohexadecenone 37609-25-9 DEFGJK 804 3-Thujopsanone 25966-79-4 BDEFHJK 872 10-epi-gamma-Eudesmol 15051-81-7 DFHJK 919 3a,4,5,6,7,7a-hexahydro-1H-4,7- 17511-60-3 CEFHJK methanoinden-6-yl propionate 927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJK hexamethylindan 933 Patchouli alcohol 5986-55-0 DEFHIJK 978 3a,4,5,6,7,7a-hexahydro-1H-4,7- 68039-44-1 DEFHJK methanoinden-6-yl pivalate 1007 (2R,4a′R,8a′R)-3,7′-dimethyl- 41816-03-9 DEFHJK 3′,4′,4a′,5′,8′,8a′-hexahydro-1′H- spiro[oxirane-2,2′- [1,4]methanonaphthalene] 1022 2,2,7,9-tetramethylspiro(5.5)undec- 502847-01-0 DHIJK 8-en-1-one 1024 (Z)-2-ethyl-4-(2,2,3- 28219-61-6 DEFHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1027 5-methoxyoctahydro-1H-4,7- 193425-86-4 CHJK methanoindene-2-carbaldehyde 1029 Sclareol oxide 5153-92-4 DEFHJK 1035 Spathulenol 6750-60-3 DEFHJK 1038 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3 DGJK 1-one 1060 Thujopsene 470-40-6 BDEFGJKL 1089 Tricyclone 68433-81-8 DEFHJK 1107 Valerianol 20489-45-6 DEFHJK 1129 1-((3R,3aR,7R,8aS)-3,6,8,8- 32388-55-9 DHJK tetramethyl-2,3,4,7,8,8a-hexahydro- 1H-3a,7-methanoazulen-5-yl)ethan- 1-one 1131 Methyl (Z)-2-(((2,4- 68738-99-8 DEFHJ dimethylcyclohex-3-en-1- yl)methylene)amino)benzoate 1136 Vetivert Acetate 117-98-6 DEFHJK 1137 Decahydro-3H-spiro[furan-2,5′- 68480-11-5 DEFGJKL [4,7]methanoindene] 1140 (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3 DEFHJK tetramethyldecahydro-1H- cyclopropa[e]azulen-4-ol 1142 3,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJ tetrahydronaphthalene-2-carbonitrile 1143 (1S,2S,3S,5R)-2,6,6- 133636-82-5 DEFHJK trimethylspiro[bicyclo[3.1.1]heptane- 3,1′-cyclohexan]-2′-en-4′-one 1144 1′,1′,5′,5′-tetramethylhexahydro- 154171-76-3 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′- [2,4a]methanonaphthalene] 1145 1′,1′,5′,5′-tetramethylhexahydro- 154171-77-4 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′- [2,4a]methanonaphthalene] K

TABLE 5 List of materials with ALL MORVs greater than 5 to 10 Number Material Name CAS Number Comment Code 248 Hydroxymethyl 59056-64-3 BDEFHJK isolongifolene

TABLE 6 List of materials with ALL MORVs from 0.5 to less than 1 Number Material Name CAS Number Comment Code 472 Decyl anthranilate 18189-07-6 DEFHJ 526 (Z)-3-methyl-2-(pent- 488-10-8 BCHIJKL 2-en-1-yl)cyclopent- 2-en-1-one

Compositions and Methods

-   A composition comprising a malodor reduction material having an MORV     of at least 0.5, from about 0.5 to about 10, from 0.5 to about 10,     from about 1 to about 10, or from about 1 to about 5 is disclosed.

In one aspect, said composition comprises a malodor reduction material is selected from the group consisting of Table 1 materials Table 2 materials, Table 3 materials and mixtures thereof; in one aspect said material is selected from the group consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29; 30; 31; 32; 33; 34; 35; 42; 49; 50; 62; 64; 65; 67; 70; 91; 92; 93; 98; 101; 102; 103; 108; 110; 114; 117; 119; 122; 123; 126; 130; 142; 145; 146; 149; 155; 159; 167; 168; 170; 178; 186; 189; 190; 192; 193; 208; 209; 210; 218; 228; 229; 231; 243; 254; 256; 259; 267; 274; 278; 280; 281; 290; 294; 317; 318; 322; 325; 333; 338; 342; 344; 358; 362; 364; 375; 386; 394; 397; 398; 415; 421; 424; 428; 429; 436; 441; 444; 445; 449; 453; 461; 466; 468; 471; 473; 474; 475; 491; 519; 520; 524; 527; 530; 531; 532; 534; 544; 546; 551; 555; 565; 578; 580; 581; 584; 586; 587; 589; 603; 604; 606; 609; 611; 612; 614; 615; 618; 621; 627; 628; 631; 632; 633; 639; 649; 659; 668; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 730; 738; 742; 748; 750; 752; 763; 766; 767; 768; 770; 774; 778; 781; 786; 791; 792; 800; 802; 806; 814; 821; 826; 827; 828; 829; 834; 837; 839; 840; 850; 852; 856; 864; 865; 866; 868; 869; 871; 873; 876; 877; 878; 879; 884; 897; 905; 914; 926; 928; 929; 937; 946; 947; 950; 955; 969; 973; 974; 982; 993; 1006; 1008; 1010; 1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062; 1064; 1066; 1067; 1070; 1072; 1073; 1077; 1078; 1082; 1102; 1104; 1105; 1120; 1125; 1137; 1138; 1144; 1145, Table 2 materials 565; 631; 659; 715, Table 3 materials 9; 12; 19; 20; 21; 24; 25; 27; 32; 34; 53; 55; 59; 64; 65; 70; 73; 81; 84; 96; 97; 98; 108; 110; 111; 114; 116; 119; 125; 126; 133; 142; 146; 147; 150; 154; 157; 159; 163; 166; 167; 169; 178; 189; 192; 194; 198; 201; 204; 205; 228; 231; 232; 237; 239; 254; 256; 258; 264; 270; 273; 282; 283; 284; 287; 290; 302; 306; 312; 319; 322; 325; 333; 338; 344; 346; 354; 358; 362; 365; 366; 375; 376; 387; 412; 419; 420; 428; 429; 437; 438; 439; 443; 444; 447; 448; 461; 469; 474; 477; 481; 491; 492; 495; 496; 509; 512; 517; 518; 522; 525; 530; 535; 536; 538; 540; 542; 544; 547; 549; 554; 555; 556; 557; 575; 576; 579; 583; 585; 588; 589; 604; 605; 609; 617; 619; 633; 640; 645; 647; 651; 652; 662; 664; 665; 667; 683; 686; 687; 693; 698; 699; 701; 717; 725; 730; 740; 742; 744; 745; 760; 761; 777; 779; 784; 789; 792; 797; 806; 810; 812; 817; 819; 820; 827; 828; 832; 835; 836; 838; 839; 845; 846; 847; 848; 850; 851; 858; 865; 875; 878; 879; 882; 883; 888; 889; 891; 899; 900; 901; 902; 903; 904; 909; 914; 931; 937; 940; 946; 947; 956; 977; 981; 986; 987; 994; 995; 1001; 1004; 1008; 1010; 1011; 1017; 1018; 1019; 1020; 1030; 1031; 1039; 1040; 1041; 1051; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1069; 1071; 1076; 1081; 1082; 1098; 1102; 1104; 1105; 1115; 1119; 1120; 1122; 1127; 1128; 1141 and mixtures thereof, in one aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29; 30; 31; 32; 34; 35; 42; 49; 50; 62; 64; 65; 67; 70; 91; 92; 93; 98; 101; 102; 103; 108; 114; 117; 122; 123; 126; 130; 142; 145; 146; 149; 155; 159; 167; 168; 170; 178; 186; 189; 190; 192; 193; 208; 209; 210; 218; 228; 229; 231; 243; 254; 256; 259; 267; 274; 278; 280; 281; 290; 294; 317; 318; 322; 325; 333; 338; 342; 344; 358; 362; 364; 375; 386; 394; 397; 398; 415; 421; 424; 428; 429; 436; 441; 444; 445; 449; 453; 461; 466; 468; 471; 473; 474; 475; 491; 519; 520; 524; 527; 530; 531; 532; 534; 544; 546; 551; 555; 565; 578; 580; 581; 584; 586; 587; 589; 603; 604; 606; 609; 611; 612; 614; 615; 618; 621; 627; 628; 631; 632; 633; 639; 649; 659; 668; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 730; 742; 748; 750; 752; 763; 766; 767; 768; 770; 774; 778; 781; 786; 791; 792; 800; 802; 806; 814; 821; 826; 827; 828; 829; 834; 837; 839; 840; 850; 852; 856; 864; 865; 866; 868; 869; 871; 873; 876; 877; 878; 879; 884; 897; 905; 914; 926; 928; 929; 937; 946; 947; 950; 955; 969; 973; 974; 982; 993; 1006; 1008; 1010; 1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062; 1066; 1067; 1070; 1072; 1073; 1077; 1078; 1082; 1102; 1104; 1105; 1120; 1125; 1137; 1138; 1144; 1145, Table 2 materials 565; 631; 659; 715, Table 3 materials 9; 12; 19; 20; 21; 24; 25; 27; 32; 34; 53; 55; 59; 64; 65; 70; 73; 81; 84; 96; 97; 98; 108; 110; 111; 114; 116; 119; 125; 126; 133; 142; 146; 147; 150; 154; 157; 159; 163; 166; 167; 169; 178; 189; 192; 194; 198; 201; 204; 205; 228; 231; 232; 237; 239; 254; 256; 258; 264; 270; 273; 282; 283; 284; 287; 290; 306; 312; 319; 322; 325; 333; 338; 344; 346; 354; 358; 362; 365; 366; 375; 376; 387; 412; 419; 420; 428; 429; 437; 438; 439; 443; 444; 447; 448; 461; 469; 474; 477; 481; 491; 492; 495; 496; 509; 512; 517; 518; 522; 525; 530; 535; 536; 538; 540; 542; 544; 547; 549; 554; 555; 556; 557; 575; 576; 579; 583; 585; 588; 589; 604; 605; 609; 617; 619; 633; 640; 645; 647; 651; 652; 662; 664; 665; 667; 683; 686; 687; 693; 698; 699; 701; 717; 725; 730; 740; 742; 744; 745; 760; 761; 777; 779; 784; 789; 792; 797; 806; 810; 812; 817; 819; 820; 827; 828; 832; 835; 836; 838; 839; 845; 846; 847; 848; 850; 851; 858; 865; 875; 878; 879; 882; 883; 888; 889; 891; 899; 900; 901; 902; 903; 904; 909; 914; 931; 937; 940; 946; 947; 956; 977; 981; 986; 987; 994; 995; 1001; 1004; 1008; 1010; 1011; 1017; 1018; 1019; 1020; 1030; 1031; 1039; 1040; 1041; 1051; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1069; 1071; 1076; 1081; 1082; 1098; 1102; 1104; 1105; 1115; 1119; 1120; 1122; 1127; 1128; 1141 and mixtures thereof, in one aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 4; 29; 30; 31; 32; 50; 65; 67; 70; 92; 93; 103; 122; 123; 145; 167; 168; 208; 210; 218; 243; 256; 278; 290; 364; 386; 394; 424; 436; 453; 468; 524; 527; 532; 578; 580; 584; 589; 609; 618; 627; 668; 683; 702; 711; 763; 767; 770; 786; 802; 821; 829; 837; 839; 840; 852; 864; 866; 869; 873; 876; 878; 905; 950; 973; 993; 1010; 1037; 1043; 1066; 1070; 1073; 1077; 1078; 1102; 1120; 1125, Table 3 materials 12; 19; 20; 24; 27; 32; 53; 55; 65; 70; 73; 97; 116; 119; 125; 154; 163; 167; 194; 198; 201; 204; 239; 256; 264; 270; 273; 282; 283; 284; 290; 319; 346; 365; 376; 387; 412; 419; 437; 439; 443; 447; 469; 477; 481; 495; 518; 525; 538; 540; 542; 547; 583; 588; 589; 609; 617; 619; 652; 683; 740; 744; 745; 760; 784; 789; 810; 812; 817; 838; 839; 847; 848; 851; 858; 875; 878; 882; 889; 891; 901; 903; 904; 940; 987; 1001; 1010; 1011; 1018; 1041; 1051; 1054; 1055; 1069; 1081; 1098; 1102; 1120; 1127; 1128; 1141.

In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 3; 7; 9; 25; 29; 30; 32; 33; 34; 35; 42; 49; 62; 65; 67; 70; 91; 92; 98; 101; 102; 103; 108; 110; 114; 117; 119; 122; 126; 130; 142; 145; 159; 167; 168; 178; 186; 189; 190; 192; 193; 208; 209; 210; 218; 228; 229; 231; 243; 254; 256; 259; 267; 274; 278; 280; 281; 290; 294; 322; 325; 333; 338; 342; 344; 358; 362; 386; 394; 397; 415; 421; 424; 428; 429; 436; 441; 444; 445; 449; 453; 461; 468; 471; 473; 474; 475; 519; 520; 527; 530; 534; 544; 546; 551; 555; 565; 578; 580; 581; 587; 589; 603; 604; 606; 609; 614; 615; 618; 621; 628; 631; 632; 633; 639; 649; 659; 668; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 730; 748; 750; 763; 766; 767; 768; 774; 778; 781; 792; 802; 806; 814; 821; 826; 827; 834; 839; 840; 850; 852; 865; 866; 868; 869; 873; 876; 877; 878; 884; 897; 905; 926; 928; 929; 950; 955; 969; 973; 974; 993; 1006; 1008; 1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1072; 1104; 1105; 1120; 1125; 1137; 1138; 1144; 1145 and table 3 materials 9; 12; 19; 21; 25; 32; 34; 53; 55; 59; 65; 70; 81; 84; 97; 98; 108; 110; 114; 116; 119; 126; 133; 142; 147; 150; 157; 159; 163; 166; 167; 178; 189; 192; 198; 201; 204; 205; 228; 231; 232; 237; 239; 254; 256; 258; 264; 270; 273; 282; 283; 290; 302; 306; 319; 322; 325; 333; 338; 344; 346; 358; 362; 365; 376; 387; 412; 420; 428; 429; 437; 438; 439; 444; 447; 461; 469; 474; 477; 481; 495; 496; 509; 512; 525; 530; 535; 536; 538; 540; 542; 544; 547; 549; 579; 583; 588; 589; 604; 605; 609; 617; 619; 633; 640; 645; 651; 652; 662; 664; 665; 667; 683; 686; 693; 698; 699; 744; 745; 760; 761; 777; 779; 784; 792; 797; 806; 810; 817; 819; 820; 827; 832; 835; 836; 838; 839; 845; 846; 847; 850; 851; 858; 865; 878; 882; 883; 888; 901; 903; 904; 909; 931; 987; 995; 1001; 1008; 1017; 1018; 1019; 1020; 1030; 1031; 1040; 1041; 1053; 1054; 1055; 1057; 1058; 1069; 1076; 1098; 1127; 1128; 1141 and mixtures thereof.

In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 33; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114; 119; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453; 457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 601; 603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143; 1144; 1145; 1147, Table 2 materials 2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097; and Table 3 materials 1; 9; 12; 13; 19; 20; 21; 24; 25; 27; 32; 38; 54; 55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105; 109; 111; 114; 119; 133; 134; 135; 137; 140; 142; 147; 148; 150; 151; 152; 153; 154; 157; 159; 162; 178; 181; 189; 191; 192; 195; 197; 204; 211; 228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273; 275; 277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 302; 306; 308; 310; 312; 319; 322; 325; 331; 333; 334; 336; 338; 339; 344; 346; 354; 355; 356; 358; 361; 362; 363; 370; 371; 372; 378; 381; 385; 387; 388; 390; 412; 413; 418; 420; 428; 429; 432; 437; 438; 444; 447; 448; 454; 455; 457; 461; 465; 467; 472; 477; 478; 479; 480; 481; 482; 495; 496; 497; 502; 503; 504; 509; 510; 512; 515; 517; 518; 522; 525; 529; 535; 536; 537; 540; 541; 544; 550; 557; 558; 559; 560; 561; 568; 571; 572; 575; 589; 592; 594; 599; 600; 602; 604; 609; 619; 620; 625; 626; 633; 641; 644; 645; 650; 653; 662; 667; 672; 673; 675; 676; 681; 686; 687; 693; 697; 698; 700; 703; 704; 706; 707; 716; 717; 718; 722; 725; 744; 745; 746; 757; 769; 771; 779; 782; 799; 806; 819; 820; 827; 828; 836; 838; 839; 847; 850; 875; 878; 879; 880; 881; 888; 889; 890; 891; 893; 899; 900; 901; 903; 909; 912; 914; 920; 922; 930; 939; 940; 941; 945; 947; 948; 953; 954; 958; 959; 960; 965; 967; 971; 986; 987; 994; 995; 998; 1000; 1001; 1003; 1005; 1008; 1009; 1010; 1011; 1017; 1018; 1023; 1031; 1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095; 1099; 1102; 1104; 1105; 1115; 1116; 1120; 1127; 1128; 1134; 1135; 1141; 1147 and mixtures thereof, in one aspect, said composition comprises a material selected from the group consisting of Table 1 materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453; 457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143; 1144; 1145; 1147, Table 2 materials 2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097; and Table 3 materials 1; 9; 12; 13; 19; 20; 21; 24; 25; 27; 32; 38; 54; 55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105; 109; 111; 114; 119; 133; 134; 135; 137; 140; 142; 147; 148; 150; 151; 152; 153; 154; 157; 159; 162; 178; 181; 189; 191; 192; 195; 197; 204; 211; 228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273; 275; 277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 306; 308; 310; 312; 319; 322; 325; 331; 333; 334; 336; 338; 339; 344; 346; 354; 355; 356; 358; 361; 362; 363; 370; 371; 372; 378; 381; 385; 387; 388; 390; 412; 413; 418; 420; 428; 429; 432; 437; 438; 444; 447; 448; 454; 455; 457; 461; 465; 467; 472; 477; 478; 479; 480; 481; 482; 495; 496; 497; 502; 503; 504; 509; 510; 512; 515; 517; 518; 522; 525; 529; 535; 536; 537; 540; 541; 544; 550; 557; 558; 559; 560; 561; 568; 571; 572; 575; 589; 592; 594; 599; 600; 602; 604; 609; 619; 620; 625; 626; 633; 641; 644; 645; 650; 653; 662; 667; 672; 673; 675; 676; 681; 686; 687; 693; 697; 698; 700; 703; 704; 706; 707; 716; 717; 718; 722; 725; 744; 745; 746; 757; 769; 771; 779; 782; 799; 806; 819; 820; 827; 828; 836; 838; 839; 847; 850; 875; 878; 879; 880; 881; 888; 889; 890; 891; 893; 899; 900; 901; 903; 909; 912; 914; 920; 922; 930; 939; 940; 941; 945; 947; 948; 953; 954; 958; 959; 960; 965; 967; 971; 986; 987; 994; 995; 998; 1000; 1001; 1003; 1005; 1008; 1009; 1010; 1011; 1017; 1018; 1023; 1031; 1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095; 1099; 1102; 1104; 1105; 1115; 1116; 1120; 1127; 1128; 1134; 1135; 1141; 1147 and mixtures thereof.

In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 4; 13; 16; 17; 18; 21; 32; 33; 34; 35; 37; 42; 49; 57; 76; 126; 145; 156; 167; 168; 174; 190; 199; 206; 208; 210; 242; 247; 249; 259; 277; 281; 286; 289; 318; 353; 370; 371; 372; 373; 378; 407; 417; 424; 425; 429; 449; 457; 468; 474; 479; 480; 482; 485; 501; 524; 527; 529; 537; 562; 578; 580; 587; 589; 592; 595; 612; 615; 618; 621; 632; 638; 639; 649; 683; 702; 711; 733; 735; 736; 741; 748; 767; 771; 786; 788; 824; 834; 839; 866; 868; 877; 905; 924; 955; 969; 974; 976; 980; 982; 993; 1016; 1037; 1038; 1042; 1060; 1075; 1077; 1078; 1090; 1091; 1117; 1137; 1146, Table 3 materials 13; 21; 27; 32; 34; 37; 73; 81; 107; 115; 125; 126; 157; 163; 167; 169; 194; 198; 201; 205; 239; 242; 277; 282; 286; 287; 289; 319; 366; 370; 371; 372; 376; 378; 407; 417; 419; 429; 437; 439; 442; 443; 457; 474; 479; 480; 482; 485; 495; 496; 509; 512; 525; 529; 537; 549; 556; 576; 579; 583; 585; 588; 589; 592; 617; 619; 638; 640; 641; 652; 664; 665; 683; 740; 743; 760; 771; 779; 784; 810; 812; 820; 839; 845; 846; 847; 858; 875; 883; 888; 901; 902; 903; 904; 940; 981; 1001; 1002; 1017; 1018; 1019; 1039; 1040; 1051; 1054; 1071; 1075; 1081; 1088; 1091; 1115; 1118; 1119; 1122; 1133; 114, and mixtures thereof, in one aspect, said composition comprises a material selected from Table 1 materials 4; 21; 32; 33; 34; 35; 42; 49; 145; 167; 168; 190; 208; 210; 259; 281; 424; 429; 449; 468; 474; 524; 527; 578; 580; 587; 589; 612; 615; 618; 621; 632; 639; 649; 683; 702; 711; 748; 767; 786; 834; 839; 866; 868; 877; 905; 955; 969; 974; 982; 993; 1016; 1037; 1060; 1077; 1078; 1137, Table 3 materials 21; 27; 32; 34; 73; 81; 125; 126; 157; 163; 167; 169; 194; 198; 201; 205; 239; 282; 287; 319; 366; 376; 419; 429; 437; 439; 443; 474; 495; 496; 509; 512; 525; 549; 556; 576; 579; 583; 585; 588; 589; 617; 619; 640; 652; 664; 665; 683; 740; 760; 779; 784; 810; 812; 820; 839; 845; 846; 847; 858; 875; 883; 888; 901; 902; 903; 904; 940; 981; 1001; 1017; 1018; 1019; 1039; 1040; 1051; 1054; 1071; 1081; 1115; 1122 and mixtures thereof.

In one aspect, said composition comprising a malodor reduction material, in one aspect, comprises a malodor reduction material having a Universal MORV.

Preferably, said composition comprising a malodor reduction material having a Universal MORV comprises a malodor reduction material selected from the group consisting of Table 4 materials 7; 229; 281; 441; 603; 621; 627; 632; 696; 708; 714; 750; 1060; 1137; 1144; 1145, and Table 6 material 627 and mixtures thereof. In one aspect, such materials are selected from Table 4 material 627 and mixtures thereof are disclosed.

In one aspect, said composition comprising a malodor reduction material having a Universal MORV. In one aspect, said composition comprises, a malodor reduction material selected from the group consisting of Table 4 materials 7; 229; 281; 441; 603; 621; 632; 696; 708; 714; 750; 1060; 1137; 1144; 1145, and mixtures thereof are disclosed.

In one aspect, said composition comprising a malodor reduction material having a Universal MORV comprises, a malodor reduction material selected from the group consisting of Table 4 materials 7; 14; 39; 48; 183; 206; 212; 215; 229; 260; 261; 329; 335; 360; 441; 484; 487; 488; 501; 566; 567; 569; 570; 573; 574; 603; 616; 621; 624; 632; 663; 680; 684; 694; 696; 708; 712; 714; 726; 750; 775; 776; 788; 804; 872; 919; 927; 933; 978; 1007; 1022; 1024; 1029; 1035; 1038; 1060; 1089; 1107; 1129; 1131; 1136; 1137; 1140; 1142; 1143; 1144; 1145, Table 5 materials 248, and Table 6 material 472 and mixtures thereof.

In one aspect, said composition comprising a malodor reduction material having a Universal MORV comprises, a malodor reduction material selected from the group consisting of Table 4 materials 199; 206; 281; 353; 501; 621; 632; 788; 1038; 1060; 1137 and mixtures thereof. In one aspect, such materials are selected from Table 4 281; 621; 632; 1060; 1137 and mixtures thereof.

A composition according to any preceding embodiment wherein said malodor reduction material is not a material selected from the group consisting of 302; 288; 50; 157; 1017; 888; 64; 1054; 832; 375; 390; 745; 504; 505; 140; 1012; 498; 362; 103; 356; 1074; 908; 1127; 475; 918; 687; 611; 317; 9; 141; 550; 602; 913; 1005; 521; 10; 215; 370; 335; 378; 1121; 360; 565; 1136; 1129; 655; 369; 1065; 914; 757; 601; 478; 889; 891; 358; 973; 162; 554; 522; 312; 125; 26; 418; 92; 586; 1026; 218; 31; 828; 871; 829; 1066; 287; 269; 769; 701; 1118; 70; 946; 142; 109; 108 and mixtures thereof.

A composition according to any preceding embodiment, said malodor reduction composition being a consumer product, said consumer comprising a total of, based on total consumer product weight, from about 0.0001% to about 100% of one or more of said malodor reduction materials and an adjunct material is disclosed.

In one aspect, said malodor reduction composition that is a consumer product is a laundry detergent that comprises a total of, based on total consumer product weight, from about 0.0001% to about 10%, in one aspect, from about 0.001% to about 5%, in one aspect, from about 0.1% to about 3%, in one aspect, from about 0.3% to about 2% of one or more of said malodor reduction materials and, a material selected from the group consisting of surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, a fabric softener active, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments and mixtures thereof, in none aspect, said laundry detergent comprises an adjunct material selected from the group consisting of an organic acid, in one aspect, citric acid and/or lactic acid, hydrogenated castor oil, ethoxylated polyethleneimines, in one aspect, PEI 600 EO 20 and/or PEI 600, an enzyme, in one aspect, a cold water amylase, cold water protease and/or xylogluconase.

In one aspect, said malodor reduction composition that is a consumer product is air care composition that comprises a total of, based on total consumer product weight, from about 0.001% to about 100%, in none apect, from 0.01 to 10%, of one or more of said malodor reduction materials and, optionally, one or more materials selected from the group consisting of surfactants, antimicrobial agents, wetting agents, buffering agents, cyclodextrins, propellants, and solvents.

In one aspect, said malodor reduction composition that is a consumer product is a liquid fabric enhancer that comprises a total of, based on total composition weight, from about 0.05% to about 10% of one or more of said malodor reduction materials and, a fabric softener active selected from the group consisting of a quaternary ammonium compound, a silicone polymer, a polysaccharide, a clay, an amine, a fatty ester, a dispersible polyolefin, a polymer latex and mixtures thereof, in one aspect, said quaternary ammonium compound is selected from the group consisting of bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester, 1,2-di(acyloxy)-3-trimethylammoniopropane chloride, N,N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride, N,N-bis(tallowoyl-oxy-ethyl) N,N-dimethyl ammonium chloride, N,N-bis(stearoyl-oxy-ethyl) N-(2 hydroxyethyl) N-methyl ammonium methylsulfate, 1,2 di (stearoyl-oxy) 3 trimethyl ammoniumpropane chloride, dicanoladimethylammonium chloride, di(hard)tallowdimethylammonium chloride dicanoladimethylammonium methylsulfate, 1-methyl-1-stearoylamidoethyl-2-stearoylimidazolinium methylsulfate, 1-tallowylamidoethyl-2-tallowylimidazoline, Dipalmethyl Hydroxyethylammoinum Methosulfate and mixtures thereof, in one aspect, said fabric softening active has an Iodine Value of between 0-140, in one aspect, 5-100, in one aspect,10-80, in one aspect, 15-70, in one aspect 18-25.

In one aspect, said malodor reduction composition that is a consumer product is a fabric enhancer solid particle or bead composition comprising from 0.05% to about 10% of one or more of said malodor reduction materials and at least about 25% PEG 8000.

In one aspect, said malodor reduction composition that is a consumer product is a soluble unit-dose composition contained within a PVA film.

In one aspect, said malodor reduction composition that is a consumer product is a fabric softener dryer added sheet composition, said fabric softener dryer added sheet composition comprising from 0.05% to about 10% of one or more of said malodor reduction materials and impregnated onto a non-woven sheet.

In one aspect, said malodor reduction composition that is a consumer product is a spray-dried laundry detergent powder, said composition comprising from about 0.05% to about 20% of one or more of said malodor reduction materials and at least 10% solids chosen from the following list or combinations thereof: sodium carbonate, sodium sulfate, carboxy methyl cellulose powder, a polymer comprising an acrylate monomer.

In one aspect, said malodor reduction composition that is a consumer product is a plastic film said plastic film comprising LLDPE, LDPE, HDPE, and/or compostable film, in one aspect, said plastic film comprises about 0.5 mg to about 100 mg of said malodor reduction composition per 20 grams of said plastic film, in one aspect, said malodor reduction composition is present in the amount of about 5 mg to about 30 mg per 20 grams of said plastic film, in one aspect, said malodor reduction composition is present in the amount of about 5 mg to about 15 mg per 20 grams of said plastic film.

In one aspect, said malodor reduction composition that is a consumer product is an absorbent article said absorbent article comprising a total of, based on total consumer product weight, from about 0.1% to about 75%, in one aspect, from about 1% to about 50%, in one aspect, from about 5% to about 40%, in one aspect, from about 12% to about 30% of one or more of said malodor reduction materials and, wherein the article comprises a topsheet, a backsheet, an absorbent core disposed between the topsheet and the backsheet, and an acquisition layer disposed between the topsheet and the absorbent core, wherein the malodor reduction composition is disposed on one of the backsheet, absorbent core, or acquisition layer, in one aspect, said absorbant article comprises a hot melt adhesive and the hot melt adhesive comprises the malodor reduction composition, in one aspect, the hot melt adhesive adheres the backsheet to the topsheet, in one aspect, the backsheet comprises a nonwoven layer and a film layer, and the hot melt adhesive adheres the backsheet nonwoven layer to the backsheet film layer.

In one aspect, said malodor reduction composition that is a consumer product is a personal care deodorant composition, said deodorant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and, optionally, from about 0.01% to about 75% of an antimicrobial, in one aspect, said antimicrobialsare selected from the group consisting of metals, zeolites, metal zeolites, quaternary ammonium (quat) compounds (e.g., cetyl pyridinium chloride, and benzylalkonium chloride), quat bound clays, metal bound clays, polyaspirin. salicylic acid, polyvinyl amines, coal tar, sulfur, whitfield's ointment, castellani's paint, aluminum chloride, gentian violet, octopirox (piroctone olamine), ciclopirox olamine, undecylenic acid and it's metal salts, potassium permanganate, selenium sulfide, sodium thiosulfate, glycols, diols, oil of bitter orange, urea preparations, griseofulvin, 8-Hydroxyquinoline ciloquinol, thiobendazole, thiocarbamates, haloprogin, polyenes, hydroxypyridone, morpholine, benzylamine, allylamines (such as terbinafine), tea tree oil, clove leaf oil, coriander, palmarosa, berberine, thyme red, cinnamon oil, citronellic acid, hinokitol, ichthyol pale, Sensiva SC-50, Elestab HP-100, azelaic acid, lyticase, iodopropynyl butylcarbamate (IPBC), triclosan, triclocarban, isothiazalinones and azoles, and combinations thereof, more preferably, hexanediol, triclosan, octyl isothiazalinone metals selected from the group consisting of Zn, Cu, Al, Ti, Sn, Bi, and Ag, metal salts selected from the group consisting of zinc carbonate, copper sulfate, and zinc gluconate, metal pyrithione salts selected from the group consisting of ZPT and CuPT, glycols selected from the group consisting of propylene glycol, dipropylene glycol and hexylene glycol and mixtures thereof, in one aspect, said personal care deodorant composition comprises, based on total deodorant weight, from about 10% to about 75% glycol.

In one aspect, said malodor reduction composition that is a consumer product is a personal care body wash/shampoo composition, said body wash/shampoo comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials from about 3% to 30% of a surfactant, and, optionally, a miscellar phase and/or lamellar phase.

In one aspect, said malodor reduction composition that is a consumer product is a personal care antiperspirant composition, said antiperspirant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and, optionally, from about 1% to about 25% of an aluminum salt antiperspirant active.

In one aspect, said malodor reduction composition that is a consumer product is an anhydrous antiperspirant composition, said anhydrous antiperspirant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and from about 1% to about 25% oof an antiperspirant actives slected from the group consisiting of astringent metallic salts, in one aspect, inorganic and organic salts of aluminum, zirconium and zinc, as well as mixtures thereof, in one aspect, aluminum halides, aluminum chlorohydrate, aluminum hydroxyhalides, zirconyl oxyhalides, zirconyl hydroxyhalides, and mixtures thereof.

In one aspect, said malodor reduction composition that is a consumer product is a dish cleaning composition, said dish cleaning composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials.

In one aspect, a method of controlling malodors comprising: contacting the material comprising a malodor with a composition selected from the group consisting of any of the compositions comprising a malodor reduction material disclosed herein and mixtures thereof, in one aspect, said contacting step comprises contacting said material containing a malodor with about 1 mg to about 50 mg, from about 3 mg to 30 mg, or from about 5 mg to about 20 mg of said composition per 20 grams of said material containing a malodor is disclosed.

In one aspect, a method of determining the material's ability to decrease or even eliminate the perception of one or more malodors comprising determining the MORV and/or Universal MORV of said material, in one aspect, determining said MORV and/or Universal MORV by the MORV and Universal MORV method provided in Test Method 1, is disclosed.

Process of Making Encapsulates

Methods of making suitable encapsulated malodor reduction compositions, for example condensation processes, as well as suitable shell materials for such encapsulated malodor reduction compositions are described in U.S. Pat. No. 6,869,923 B1 and US Published Patent Applications Nos. 2005/0276831 A1 and 2007/020263 A1. Such shell materials include acrylates, acrylics, aminoplast materials such as melamine formaldehyde material and combinations thereof. Suitable equipment for use in the processes disclosed herein may include continuous stirred tank reactors, homogenizers, turbine agitators, recirculating pumps, paddle mixers, ploughshear mixers, ribbon blenders, vertical axis granulators and drum mixers, both in batch and, where available, in continuous process configurations, spray dryers, and extruders. Such equipment can be obtained from Lodige GmbH (Paderborn, Germany), Littleford Day, Inc. (Florence, Ky., U.S.A.), Forberg AS (Larvik, Norway), Glatt Ingenieurtechnik GmbH (Weimar, Germany), Niro (Soeborg, Denmark), Hosokawa Bepex Corp. (Minneapolis, Minn., U.S.A.), Arde Barinco (N.J., U.S.A.).

Adjunct Materials

While not essential for the purposes of the present invention, the non-limiting list of adjuncts illustrated hereinafter are suitable for use in the instant compositions and may be desirably incorporated in certain aspects of the invention, for example to assist or enhance cleaning performance, for treatment of the substrate to be cleaned, or to modify the aesthetics of the composition as is the case with perfumes, colorants, dyes or the like. The precise nature of these additional components, and levels of incorporation thereof, will depend on the physical form of the composition and the nature of the fabric treatment operation for which it is to be used. Suitable adjunct materials include, but are not limited to, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments and/or fabric softener actives.

As stated, the adjunct ingredients are not essential to Applicants' compositions. Thus, certain aspects of Applicants' compositions do not contain one or more of the following adjuncts materials: surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems structure elasticizing agents, carriers, hydrotropes, processing aids, solvents, pigments and/or fabric softener actives. However, when one or more adjuncts are present, such one or more adjuncts may be present as detailed below.

Hueing Dye—The liquid laundry detergent composition may comprise a hueing dye. The hueing dyes employed in the present laundry care compositions may comprise polymeric or non-polymeric dyes, organic or inorganic pigments, or mixtures thereof. In one aspect, the hueing dye comprises a polymeric dye, comprising a chromophore constituent and a polymeric constituent. The chromophore constituent is characterized in that it absorbs light in the wavelength range of blue, red, violet, purple, or combinations thereof upon exposure to light. In one aspect, the chromophore constituent exhibits an absorbance spectrum maximum from about 520 nanometers to about 640 nanometers in water and/or methanol, and in another aspect, from about 560 nanometers to about 610 nanometers in water and/or methanol.

Although any suitable chromophore may be used, the dye chromophore is, in one aspect, selected from benzodifuranes, methine, triphenylmethanes, napthalimides, pyrazole, napthoquinone, anthraquinone, azo, oxazine, azine, xanthene, triphenodioxazine and phthalocyanine dye chromophores. Mono and di-azo dye chromophores are may be preferred.

The hueing dye may comprise a dye polymer comprising a chromophore covalently bound to one or more of at least three consecutive repeat units. It should be understood that the repeat units themselves do not need to comprise a chromophore. The dye polymer may comprise at least 5, or at least 10, or even at least 20 consecutive repeat units.

The repeat unit can be derived from an organic ester such as phenyl dicarboxylate in combination with an oxyalkyleneoxy and a polyoxyalkyleneoxy. Repeat units can be derived from alkenes, epoxides, aziridine, carbohydrate including the units that comprise modified celluloses such as hydroxyalkylcellulose; hydroxypropyl cellulose; hydroxypropyl methylcellulose; hydroxybutyl cellulose; and, hydroxybutyl methylcellulose or mixtures thereof. The repeat units may be derived from alkenes, or epoxides or mixtures thereof. The repeat units may be C₂-C₄ alkyleneoxy groups, sometimes called alkoxy groups, in one aspect, derived from C₂-C₄ alkylene oxide. The repeat units may be C₂-C₄ alkoxy groups, in one aspect, ethoxy groups.

For the purposes of the present invention, the at least three consecutive repeat units form a polymeric constituent. The polymeric constituent may be covalently bound to the chromophore group, directly or indirectly via a linking group. Examples of suitable polymeric constituents include polyoxyalkylene chains having multiple repeating units. In one aspect, the polymeric constituents include polyoxyalkylene chains having from 2 to about 30 repeating units, from 2 to about 20 repeating units, from 2 to about 10 repeating units or even from about 3 or 4 to about 6 repeating units. Non-limiting examples of polyoxyalkylene chains include ethylene oxide, propylene oxide, glycidol oxide, butylene oxide and mixtures thereof.

Surfactants—The compositions according to the present invention may comprise a surfactant or surfactant system wherein the surfactant can be selected from nonionic surfactants, anionic surfactants, cationic surfactants, ampholytic surfactants, zwitterionic surfactants, semi-polar nonionic surfactants and mixtures thereof.

The surfactant is typically present at a level of from about 0.1% to about 60%, from about 1% to about 50% or even from about 5% to about 40% by weight of the subject composition.

Chelating Agents—The compositions herein may contain a chelating agent. Suitable chelating agents include copper, iron and/or manganese chelating agents and mixtures thereof. When a chelating agent is used, the composition may comprise from about 0.1% to about 15% or even from about 3.0% to about 10% chelating agent by weight of the subject composition.

Dye Transfer Inhibiting Agents—The compositions of the present invention may also include one or more dye transfer inhibiting agents. Suitable polymeric dye transfer inhibiting agents include, but are not limited to, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof.

When present in a subject composition, the dye transfer inhibiting agents may be present at levels from about 0.0001% to about 10%, from about 0.01% to about 5% or even from about 0.1% to about 3% by weight of the composition.

Dispersants—The compositions of the present invention can also contain dispersants. Suitable water-soluble organic materials include the homo- or co-polymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms.

Perfumes—The dispersed phase may comprise a perfume that may include materials selected from the group consisting of perfumes such as 3-(4-t-butylphenyl)-2-methyl propanal, 3-(4-t-butylphenyl)-propanal, 3-(4-isopropylphenyl)-2-methylpropanal, 3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and 2,6-dimethyl-5-heptenal, α-damascone, β-damascone, δ-damascone, β-damascenone, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one, 2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one, 2-sec-butylcyclohexanone, and β-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol.

Perfume Delivery Technologies—The compositions of the present invention may comprise one or more perfume delivery technologies that stabilize and enhance the deposition and release of perfume ingredients from treated substrate. Such perfume delivery technologies can also be used to increase the longevity of perfume release from the treated substrate. Perfume delivery technologies, methods of making certain perfume delivery technologies and the uses of such perfume delivery technologies are disclosed in US 2007/0275866 A1.

In one aspect, the compositions of the present invention may comprise from about 0.001% to about 20%, or from about 0.01% to about 10%, or from about 0.05% to about 5%, or even from about 0.1% to about 0.5% by weight of the perfume delivery technology. In one aspect, said perfume delivery technologies may be selected from the group consisting of: perfume microcapsules, pro-perfumes, polymer particles, functionalized silicones, polymer assisted delivery, molecule assisted delivery, fiber assisted delivery, amine assisted delivery, cyclodextrins, starch encapsulated accord, zeolite and inorganic carrier, and mixtures thereof:

In one aspect, said perfume delivery technology may comprise microcapsules formed by at least partially surrounding a benefit agent with a wall material. Said benefit agent may include materials selected from the group consisting of perfumes such as 3-(4-t-butylphenyl)-2-methyl propanal, 3-(4-t-butylphenyl)-propanal, 3-(4-isopropylphenyl)-2-methylpropanal, 3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and 2,6-dimethyl-5-heptenal, α-damascone, β-damascone, δ-damascone, β-damascenone, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one, 2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one, 2-sec-butylcyclohexanone, and β-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol. Suitable perfume materials can be obtained from Givaudan Corp. of Mount Olive, N.J., USA, International Flavors & Fragrances Corp. of South Brunswick, N.J., USA, or Quest Corp. of Naarden, Netherlands. In one aspect, the microcapsule wall material may comprise: melamine, polyacrylamide, silicones, silica, polystyrene, polyurea, polyurethanes, polyacrylate based materials, gelatin, styrene malic anhydride, polyamides, and mixtures thereof. In one aspect, said melamine wall material may comprise melamine crosslinked with formaldehyde, melamine-dimethoxyethanol crosslinked with formaldehyde, and mixtures thereof. In one aspect, said polystyrene wall material may comprise polyestyrene cross-linked with divinylbenzene. In one aspect, said polyurea wall material may comprise urea crosslinked with formaldehyde, urea crosslinked with gluteraldehyde, and mixtures thereof. In one aspect, said polyacrylate based materials may comprise polyacrylate formed from methylmethacrylate/dimethylaminomethyl methacrylate, polyacrylate formed from amine acrylate and/or methacrylate and strong acid, polyacrylate formed from carboxylic acid acrylate and/or methacrylate monomer and strong base, polyacrylate formed from an amine acrylate and/or methacrylate monomer and a carboxylic acid acrylate and/or carboxylic acid methacrylate monomer, and mixtures thereof. In one aspect, the perfume microcapsule may be coated with a deposition aid, a cationic polymer, a non-ionic polymer, an anionic polymer, or mixtures thereof. Suitable polymers may be selected from the group consisting of: polyvinylformaldehyde, partially hydroxylated polyvinylformaldehyde, polyvinylamine, polyethyleneimine, ethoxylated polyethyleneimine, polyvinylalcohol, polyacrylates, and combinations thereof. In one aspect, the microcapsule may be a perfume microcapsule. In one aspect, one or more types of microcapsules, for example two microcapsules types having different benefit agents may be used.

In one aspect, said perfume delivery technology may comprise an amine reaction product (ARP) or a thio reaction product. One may also use “reactive” polymeric amines and or polymeric thiols in which the amine and/or thiol functionality is pre-reacted with one or more PRMs to form a reaction product. Typically the reactive amines are primary and/or secondary amines, and may be part of a polymer or a monomer (non-polymer). Such ARPs may also be mixed with additional PRMs to provide benefits of polymer-assisted delivery and/or amine-assisted delivery. Nonlimiting examples of polymeric amines include polymers based on polyalkylimines, such as polyethyleneimine (PEI), or polyvinylamine (PVAm). Nonlimiting examples of monomeric (non-polymeric) amines include hydroxyl amines, such as 2-aminoethanol and its alkyl substituted derivatives, and aromatic amines such as anthranilates. The ARPs may be premixed with perfume or added separately in leave-on or rinse-off applications. In another aspect, a material that contains a heteroatom other than nitrogen and/or sulfur, for example oxygen, phosphorus or selenium, may be used as an alternative to amine compounds. In yet another aspect, the aforementioned alternative compounds can be used in combination with amine compounds. In yet another aspect, a single molecule may comprise an amine moiety and one or more of the alternative heteroatom moieties, for example, thiols, phosphines and selenols. The benefit may include improved delivery of perfume as well as controlled perfume release. Suitable ARPs as well as methods of making same can be found in USPA 2005/0003980 A1 and U.S. Pat. No. 6,413,920 B1.

Fabric Softening Actives

The compositions of the present invention may comprise a fabric softening active (“FSA”). Suitable fabric softening actives, include, but are not limited to, materials selected from the group consisting of quaternary ammonium compounds (quat), amines, fatty esters, sucrose esters, silicones, dispersible polyolefins, clays, polysaccharides, fatty acids, softening oils, polymer latexes and mixtures thereof.

Non-limiting examples of water insoluble fabric care benefit agents include dispersible polyethylene and polymer latexes.

Quat—Suitable quats include but are not limited to, materials selected from the group consisting of ester quats, amide quats, imidazoline quats, alkyl quats, amdioester quats and mixtures thereof. Suitable ester quats include but are not limited to, materials selected from the group consisting of monoester quats, diester quats, triester quats and mixtures thereof. In one aspect, a suitable ester quat is bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester having a molar ratio of fatty acid moieties to amine moieties of from 1.85 to 1.99, an average chain length of the fatty acid moieties of from 16 to 18 carbon atoms and an iodine value of the fatty acid moieties, calculated for the free fatty acid, of from 0.5 to 60 or 15 to 50. In one aspect, the cis-trans-ratio of double bonds of unsaturated fatty acid moieties of the bis (2 hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester is from 55:45 to 75:25, respectively. Suitable amide quats include but are not limited to, materials selected from the group consisting of monoamide quats, diamide quats and mixtures thereof. Suitable alkyl quats include but are not limited to, materials selected from the group consisting of mono alkyl quats, dialkyl quats quats, trialkyl quats, tetraalkyl quats and mixtures thereof.

In one embodiment, the fabric softening active is a quaternary ammonium compound suitable for softening fabric in a rinse step. In one embodiment, the fabric softening active is formed from a reaction product of a fatty acid and an aminoalcohol obtaining mixtures of mono-, di-, and, in one embodiment, tri-ester compounds. In another embodiment, the fabric softening active comprises one or more softener quaternary ammonium compounds such, but not limited to, as a monoalkyquaternary ammonium compound, dialkylquaternary ammonium compound, a diamido quaternary compound, a diester quaternary ammonium compound, or a combination thereof.

In one aspect, the fabric softening active comprises a diester quaternary ammonium or protonated diester ammonium (hereinafter “DQA”) compound composition. In certain embodiments of the present invention, the DQA compound compositions also encompass diamido fabric softening actives s and fabric softening actives with mixed amido and ester linkages as well as the aforementioned diester linkages, all herein referred to as DQA.

In one embodiment, the fabric softening agent is chosen from at least one of the following: ditallowoyloxyethyl dimethyl ammonium chloride, dihydrogenated-tallowoyloxyethyl dimethyl ammonium chloride, ditallow dimethyl ammonium chloride, dihydrogenatedtallow dimethyl ammonium chloride, ditallowoyloxyethyl methylhydroxyethylammonium methyl sulfate, dihydrogenated-tallowoyloxyethyl methyl hydroxyethylammonium chloride, or combinations thereof.

It will be understood that combinations of softener actives disclosed above are suitable for use in this invention.

Anion A

In the cationic nitrogenous salts herein, the anion A⁻, which comprises any softener compatible anion, provides electrical neutrality. Most often, the anion used to provide electrical neutrality in these salts is from a strong acid, especially a halide, such as chloride, bromide, or iodide. However, other anions can be used, such as methylsulfate, ethylsulfate, acetate, formate, sulfate, carbonate, fatty acid anions and the like. In one aspect, the anion A may comprise chloride or methylsulfate. The anion, in some aspects, may carry a double charge. In this aspect, A⁻ represents half a group.

Silicone

In one embodiment, the compositions of the present invention may comprise a silicone. Suitable levels of silicone may comprise from about 0.1% to about 70%, alternatively from about 0.3% to about 40%, alternatively from about 0.5% to about 30%, alternatively from about 1% to about 20% by weight of the composition. Useful silicones can be any silicone comprising compound. In one embodiment, the silicone polymer is selected from the group consisting of cyclic silicones, polydimethylsiloxanes, aminosilicones, cationic silicones, silicone polyethers, silicone resins, silicone urethanes, and mixtures thereof. In one embodiment, the silicone is a polydialkylsilicone, alternatively a polydimethyl silicone (polydimethyl siloxane or “PDMS”), or a derivative thereof. In another embodiment, the silicone is chosen from an aminofunctional silicone, amino-polyether silicone, alkyloxylated silicone, cationic silicone, ethoxylated silicone, propoxylated silicone, ethoxylated/propoxylated silicone, quaternary silicone, or combinations thereof.

In another embodiment, the silicone may be chosen from a random or blocky organosilicone polymer having the following formula:

[R₁R₂R₃SiO_(1/2)]_((j+2))[(R₄Si(X—Z)O_(2/2)]_(k)[R₄R₄SiO_(2/2)]_(m)[R₄SiO_(3/2)]_(j)

wherein:

-   -   j is an integer from 0 to about 98; in one aspect j is an         integer from 0 to about 48; in one aspect, j is 0;     -   k is an integer from 0 to about 200, in one aspect k is an         integer from 0 to about 50; when k=0, at least one of R₁, R₂ or         R₃ is —X—Z;     -   m is an integer from 4 to about 5,000; in one aspect m is an         integer from about 10 to about 4,000; in another aspect m is an         integer from about 50 to about 2,000;         -   R₁, R₂ and R₃ are each independently selected from the group             consisting of H, OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl,             C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl,             C₆-C₃₂ alkylaryl, C₆-C₃₂ substituted alkylaryl, C₁-C₃₂             alkoxy, C₁-C₃₂ substituted alkoxy and X—Z;         -   each R₄ is independently selected from the group consisting             of H, OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ or             C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂             alkylaryl, C₆-C₃₂ substituted alkylaryl, C₁-C₃₂ alkoxy and             C₁-C₃₂ substituted alkoxy;         -   each X in said alkyl siloxane polymer comprises a             substituted or unsubstituted divalent alkylene radical             comprising 2-12 carbon atoms, in one aspect each divalent             alkylene radical is independently selected from the group             consisting of —(CH₂)_(s)— wherein s is an integer from about             2 to about 8, from about 2 to about 4; in one aspect, each X             in said alkyl siloxane polymer comprises a substituted             divalent alkylene radical selected from the group consisting             of: —CH₂—CH(OH)—CH₂—; —CH₂—CH₂—CH(OH)—; and

-   -   -   each Z is selected independently from the group consisting             of

with the proviso that when Z is a quat, Q cannot be an amide, imine, or urea moiety and if Q is an amide, imine, or urea moiety, then any additional Q bonded to the same nitrogen as said amide, imine, or urea moiety must be H or a C₁-C₆ alkyl, in one aspect, said additional Q is H; for Z A^(n−) is a suitable charge balancing anion. In one aspect A^(n−) is selected from the group consisting of Cl⁻, Br⁻, I⁻, methylsulfate, toluene sulfonate, carboxylate and phosphate; and at least one Q in said organosilicone is independently selected from —CH₂—CH(OH)—CH₂—R₅;

-   -   -   each additional Q in said organosilicone is independently             selected from the group comprising of H, C₁-C₃₂ alkyl,             C₁-C₃₂ substituted alkyl, C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or             C₆-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl, C₆-C₃₂             substituted alkylaryl, —CH₂—CH(OH)—CH₂—R₅;

-   -   -   wherein each R₅ is independently selected from the group             consisting of H, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl,             C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl,             C₆-C₃₂ alkylaryl, C₆-C₃₂ substituted alkylaryl,             —(CHR₆—CHR₆—O—)_(w)-L and a siloxyl residue;         -   each R₆ is independently selected from H, C₁-C₁₈ alkyl         -   each L is independently selected from —C(O)—R₇ or R₇;         -   w is an integer from 0 to about 500, in one aspect w is an             integer from about 1 to about 200; in one aspect w is an             integer from about 1 to about 50;         -   each R₇ is selected independently from the group consisting             of H; C₁-C₃₂ alkyl; C₁-C₃₂ substituted alkyl, C₅-C₃₂ or             C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂             alkylaryl; C₆-C₃₂ substituted alkylaryl and a siloxyl             residue;         -   each T is independently selected from H, and

and wherein each v in said organosilicone is an integer from 1 to about 10, in one aspect, v is an integer from 1 to about 5 and the sum of all v indices in each Q in the said organosilicone is an integer from 1 to about 30 or from 1 to about 20 or even from 1 to about 10.

In another embodiment, the silicone may be chosen from a random or blocky organosilicone polymer having the following formula:

[R₁R₂R₃SiO_(1/2)]_((j+2))[(R₄Si(X—Z)O_(2/2)]_(k)[R₄R₄SiO_(2/2)]_(m)[R₄SiO_(3/2)]_(j)

wherein

-   -   j is an integer from 0 to about 98; in one aspect j is an         integer from 0 to about 48; in one aspect, j is 0;     -   k is an integer from 0 to about 200; when k=0, at least one of         R₁, R₂ or R₃═—X—Z, in one aspect, k is an integer from 0 to         about 50     -   m is an integer from 4 to about 5,000; in one aspect m is an         integer from about 10 to about 4,000; in another aspect m is an         integer from about 50 to about 2,000;         -   R₁, R₂ and R₃ are each independently selected from the group             consisting of H, OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl,             C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl,             C₆-C₃₂ alkylaryl, C₆-C₃₂ substituted alkylaryl, C₁-C₃₂             alkoxy, C₁-C₃₂ substituted alkoxy and X—Z;         -   each R₄ is independently selected from the group consisting             of H, OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ or             C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂             alkylaryl, C₆-C₃₂ substituted alkylaryl, C₁-C₃₂ alkoxy and             C₁-C₃₂ substituted alkoxy;         -   each X comprises of a substituted or unsubstituted divalent             alkylene radical comprising 2-12 carbon atoms; in one aspect             each X is independently selected from the group consisting             of —(CH₂)_(s)—O—; —CH₂—CH(OH)—CH₂—O—;

-   -   -   wherein each s independently is an integer from about 2 to             about 8, in one aspect s is an integer from about 2 to about             4;         -   At least one Z in the said organosiloxane is selected from             the group consisting of R₅;

provided that when X is

then Z═—OR₅ or

-   -   -   wherein A⁻ is a suitable charge balancing anion. In one             aspect A⁻ is selected from the group consisting of Cl⁻, Br⁻,         -   I⁻, methylsulfate, toluene sulfonate, carboxylate and             phosphate and         -   each additional Z in said organosilicone is independently             selected from the group comprising of H, C₁-C₃₂ alkyl,             C₁-C₃₂ substituted alkyl, C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or             C₆-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl, C₆-C₃₂             substituted alkylaryl, R₅,

provided that when X is

then Z═—OR₅ or

-   -   -   each R₅ is independently selected from the group consisting             of H; C₁-C₃₂ alkyl; C₁-C₃₂ substituted alkyl, C₅-C₃₂ or             C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl or C₆-C₃₂             alkylaryl, or C₆-C₃₂ substituted alkylaryl,         -   —(CHR₆—CHR₆—O—)_(w)—CHR₆—CHR₆-L and siloxyl residue wherein             each L is independently selected from —O—C(O)—R₇ or —O—R₇;

-   -   -   w is an integer from 0 to about 500, in one aspect w is an             integer from 0 to about 200, one aspect w is an integer from             0 to about 50;         -   each R₆ is independently selected from H or C₁-C₁₈ alkyl;         -   each R₇ is independently selected from the group consisting             of H; C₁-C₃₂ alkyl; C₁-C₃₂ substituted alkyl, C₅-C₃₂ or             C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂             alkylaryl, and C₆-C₃₂ substituted aryl, and a siloxyl             residue;         -   each T is independently selected from H;

-   -   -   wherein each v in said organosilicone is an integer from 1             to about 10, in one aspect, v is an integer from 1 to about             5 and the sum of all v indices in each Z in the said             organosilicone is an integer from 1 to about 30 or from 1 to             about 20 or even from 1 to about 10.

In one embodiment, the silicone is one comprising a relatively high molecular weight. A suitable way to describe the molecular weight of a silicone includes describing its viscosity. A high molecular weight silicone is one having a viscosity of from about 10 cSt to about 3,000,000 cSt, or from about 100 cSt to about 1,000,000 cSt, or from about 1,000 cSt to about 600,000 cSt, or even from about 6,000 cSt to about 300,000 cSt,

-   In one embodiment, the silicone comprises a blocky cationic     organopolysiloxane having the formula:

M_(w)D_(x)T_(y)Q_(z)

-   wherein: -   M=[SiR₁R₂R₃O_(1/2)], [SiR₁R₂G₁O_(1/2)], [SiR₁G₁G₂O_(1/2)],     [SiG₁G₂G₃O_(1/2)], or combinations thereof; -   D=[SiR₁R₂O_(2/2)], [SiR₁G₁O_(2/2)], [SiG₁G₂O_(2/2)] or combinations     thereof; -   T=[SiR₁O_(3/2)], [SiG₁O_(3/2)] or combinations thereof; -   Q=[SiO_(4/2)]; -   w=is an integer from 1 to (2+y+2z); -   x=is an integer from 5 to 15,000; -   y=is an integer from 0 to 98; -   z=is an integer from 0 to 98; -   R₁, R₂ and R₃ are each independently selected from the group     consisting of H, OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂     or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl,     C₆-C₃₂ substituted alkylaryl, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted     alkoxy, C₁-C₃₂ alkylamino, and C₁-C₃₂ substituted alkylamino; -   at least one of M, D, or T incorporates at least one moiety G₁, G₂     or G_(3;) and G₁, G₂, and G₃ are each independently selected from     the formula:

-   wherein: -   X comprises a divalent radical selected from the group consisting of     C₁-C₃₂ alkylene, C₁-C₃₂ substituted alkylene, C₅-C₃₂ or C₆-C₃₂     arylene, C₅-C₃₂ or C₆-C₃₂ substituted arylene, C₆-C₃₂ arylalkylene,     C₆-C₃₂ substituted arylalkylene, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted     alkoxy, C₁-C₃₂ alkyleneamino, C₁-C₃₂ substituted alkyleneamino,     ring-opened epoxide, and ring-opened glycidyl, with the proviso that     if X does not comprise a repeating alkylene oxide moiety then X can     further comprise a heteroatom selected from the group consisting of     P, N and O; -   each R₄ comprises identical or different monovalent radicals     selected from the group consisting of H, C₁-C₃₂ alkyl, C₁-C₃₂     substituted alkyl, C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂     substituted aryl, C₆-C₃₂ alkylaryl, and C₆-C₃₂ substituted     alkylaryl; -   E comprises a divalent radical selected from the group consisting of     C₁-C₃₂ alkylene, C₁-C₃₂ substituted alkylene, C₅-C₃₂ or C₆-C₃₂     arylene, C₅-C₃₂ or C₆-C₃₂ substituted arylene, C₆-C₃₂ arylalkylene,     C₆-C₃₂ substituted arylalkylene, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted     alkoxy, C₁-C₃₂ alkyleneamino, C₁-C₃₂ substituted alkyleneamino,     ring-opened epoxide and ring-opened glycidyl, with the proviso that     if E does not comprise a repeating alkylene oxide moiety then E can     further comprise a heteroatom selected from the group consisting of     P, N, and O; -   E′ comprises a divalent radical selected from the group consisting     of C₁-C₃₂ alkylene, C₁-C₃₂ substituted alkylene, C₅-C₃₂ or C₆-C₃₂     arylene, C₅-C₃₂ or C₆-C₃₂ substituted arylene, C₆-C₃₂ arylalkylene,     C₆-C₃₂ substituted arylalkylene, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted     alkoxy, C₁-C₃₂ alkyleneamino, C₁-C₃₂ substituted alkyleneamino,     ring-opened epoxide and ring-opened glycidyl, with the proviso that     if E′ does not comprise a repeating alkylene oxide moiety then E′     can further comprise a heteroatom selected from the group consisting     of P, N, and O; -   p is an integer independently selected from 1 to 50; -   n is an integer independently selected from 1 or 2; -   when at least one of G₁, G₂, or G₃ is positively charged, A^(−t) is     a suitable charge balancing anion or anions such that the total     charge, k, of the charge-balancing anion or anions is equal to and     opposite from the net charge on the moiety G₁, G₂ or G_(3;) wherein     t is an integer independently selected from 1, 2, or 3; and     k≦(p*2/t)+1; such that the total number of cationic charges balances     the total number of anionic charges in the organopolysiloxane     molecule; and wherein at least one E does not comprise an ethylene     moiety.

Test Methods

-   Malodor reduction materials may be separated from mixtures,     including but not limited to finished products such as consumer     products and indentified, by analytical methods that include GC-MS     and/or NMR.

MORV and Universal MORV Calculation

-   1.) Search Chemical Abstracts using the name and/or the CAS Registry     number for the material of interest and use the structure provided.     If there are multiple isomers for a given material, use the     structure provided by Chemical Abstracts or use the isomer that is     most prevalent in the material. Input structure of material into     winMolconn (Hall Associates, version 1.1.2.1). -   2.) Input values from 1.) above into the following four equations:

a) MORV=−8.5096+2.8597×(dxp9)+1.1253×(knotpv)−0.34484×(e1C2O2)−0.00046231×(idw)+3.3509×(idcbar)+0.11158×(n2pag22)

b) MORV=−5.2917+2.1741×(dxvp5)−2.6595×(dxvp8)+0.45297×(e1C2C2d)−0.6202×(c1C2O2)+1.3542×(CdCH2)+0.68105×(CaasC)+1.7129×(idcbar)

c) MORV=−0.0035+0.8028×(SHCsatu)+2.1673×(xvp7)−1.3507×(c1C1C3d)+0.61496×(c1C1O2)+0.00403×(idc)−0.23286×(nd2).

d) MORV=−0.9926−0.03882×(SdO)+0.1869×(Ssp3OH)+2.1847×(xp7)+0.34344×(e1C3O2)−0.45767×(c1C2C3)+0.7684×(CKetone)

-   Equation a) is for the malodor trans-3-methyl-2-hexenoic acid     (carboxylic acid based malodors) -   Equation b) is for the malodor trimethylamine (amine based malodors) -   Equation c) is for the malodor 3-mercapto-3-methylhexan-1-ol (thiol     based malodors) -   Equation d) is for the malodor skatole (indole based malodors) -   3.) For purpose of the present application, a material's MORV is the     highest MORV value from equations 2.)a) through 2.)d). -   4.) If all MORV values from equations 2.)a) through 2.)d) above are     greater than 0.5, the subject material has a Universal MORV.

EXAMPLE 1 Malodor Reduction Composition

MRC A MRC B MRC C Ingredient CAS # Percent Percent Percent 5-Cyclohexadecen-1-One 37609-25-9 15.0 2.00 2.00 decahydro-2,2,7,7,8,9,9- 476332-65-7 0.005 0.01 0.01 heptamethylindeno(4,3a-b)furan 2,3-Dihydro-5,6-dimethoxy-2-(4- 33704-61-9 0.3 0.5 0.5 piperidinylmethylene)-1H-inden-1-one Cedryl Methyl Ether 19870-74-7 6.0 10.0 4.0 Trans-4-Decenal 65405-70-1 0.005 0.002 0.002 Decyl Aldehyde 112-31-2 3.74 2.0 2.0 3-methyl cyclopentadecenone 63314-79-4 0.4 1.0 1.0 Diphenyl Oxide 101-84-8 0.5 1.0 1.0 3a,4,5,6,7,7a-hexahydro-4,7-methano- 54830-99-8 5.0 8.0 8.0 1H-indenyl acetate 3a,4,5,6,7,7a-hexahydro-1H-4,7- 68912-13-0 6.0 8.0 8.0 methanoinden-1-yl propanoate 2-(5-methyl-2-propan-2-yl-8- 68901-32-6 10.0 15.0 15.0 bicyclo[2.2.2]oct-5-enyl)-1,3-dioxolane (E)-3,7-dimethyl-2,6- 3681-73-0 10.0 10.0 16.0 octadienylhexadecanoate Iso Nonyl Acetate 58430-94-7 6.65 8.0 3.0 2,2,7,7- 23787-90-8 10.0 8.0 8.0 tetramethyltricyclo[6.2.1.01,6]undecan- 5-one (1-Methyl-2-(1,2,2- 198404-98-7 0.1 0.3 0.3 trimethylbicyclo[3.1.0]-hex-3- ylmethyl)cyclopropyl)methanol Lauric Aldehyde 112-54-9 0.625 1.0 0.7 Methyl Iso Eugenol 93-16-3 18.000 10.0 13.0 Methyl hexadecanoate 112-39-0 3.000 10.0 12.0 2,3-dihydro-1,1-1H-dimethyl-indene- 300371-33-9 0.400 0.0 0.3 ar-propanal 4-tert-butylcyclohexanol 98-52-2 0.400 0.1 0.1 2-isobutyl-4-hydroxy-4- 63500-71-0 1.600 2.0 2.0 methyltetrahydropyran Undecyl Aldehyde 112-44-7 1.725 2.888 1.888 Undecylenic Aldehyde 112-45-8 0.550 0.2 1.2 Total 100 100.0 100.0

The term “air refresher” or “air freshener”, as used herein, refer to any suitable composition that reduces odors in air, and/or reduces the impression of odors in the air by masking, layering or including malodor counteractant perfume raw materials into the composition.

EXAMPLE 2.1-2.3 Energized Air Refresher

An energized air refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.

Example Example Example 2.1 2.2 2.3 Perfume composition 40-60 50-60 30-50 Malodor reducing composition 10-20 15-30 10-25 Functional Perfume Component 30-50 10-30 25-60

Use of Functional Perfume Components at the recited levels may help modulate the evaporation profile of an entire perfume composition to provide perfume character consistency over the intended usage period.

-   Suitable FPCs may be highly volatile, low boiling, perfume     ingredients. Non-limiting, suitable FPCs include iso-nonyl acetate,     dihydro myrcenol (3-methylene-7-methyloctan-7-ol), linalool     (3-hydroxy-3,7-dimethyl-1,6 octadiene), geraniol (3,7     dimethyl-2,6-octadien-1-ol), d-limonene,     1-methyl-4-isopropenyl-1-cyclohexene, benzyl acetate, isopropyl     mystristate, and combinations thereof.

Functional Perfume Component Examples 2.1-2.3

Example A1 Example A2 Example A3 Benzyl alcohol 10-50 0-50 0-20 Iso nonyl acetate  1-20 1-10 1-10 Dipropylene glycol methyl 40-70 5-65 2-50 ether

An energized air freshening device is filled with the composition above. The resulting air freshener is effective at reducing malodor.

EXAMPLES 3.1-3.3 Non-Energized Air Freshener

A non-energized air refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.

Example Example Example 3.1 3.2 3.3 Perfume composition 20-30 20-50 10-30 Malodor reducing composition 10-20 10-20 20-50 Functional Perfume components  0-70 40-70 20-70 Example Example Example Functional Perfume components 1 2 3 3a,4,5,6,7,7a-hexahydro-1H-4,7- 15-25 20-25 0-20 methanoinden-1-yl propanoate Iso nonyl acetate 30-75 15-75 1-10 2-isobutyl-4-hydroxy-4- 20-30  5-65 2-50 methyltetrahydropyran

-   A non-energized air freshener is filled with the example composition     above. The resulting air freshener is effective at reducing malodor.

EXAMPLES 4.1-4.2 Fabric and Air Refresher Composition

A fabric refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.

Example Example Example 4.3 Ingredient 4.1 4.2 (ranges) Deionized Water Balance Balance Balance Ethanol 3.0 3.0 1-5.0% Lupasol HF+ 0.0650 0.0650 0-0.1% Diethylene Glycol 0.175 0.175 0-0.2% Silwet L-7600 0.1 0.100 0-0.2  Maleic Acid and/or Citric 0.05 0.05 0-0.2  Acid Koralone B-119 0.015 0.015 0-0.1  Hydroxypropyl β-cyclodextrin 0.630 0.630 0-2.0% Sodium Hydroxide 0.003 0.003 0.001-0.01    Fragrance 0 0.4% 0-1.0% Malodor Reduction Composi- 0.03% 0.04% 0-0.1% tion (MRC A, B, or C) Total 100.000 100.000 100.000 Lupasol HF Polyethyleneimine (available from BASF) Silwet L-7600 Organosilicone (available from BASF) Koralone B-119 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water (available from Dow Chemical)

The resulting Fabric fresher composition is effective at reducing or preventing malodor when sprayed on fabrics, such as articles of clothing or upholstery.

EXAMPLE 5.1-5.2 Aerosol Air Freshener Composition

An aerosol air freshener composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.

Ingredient Example 5.1 Example 5.2 Water Purified USP Balance 92.370 Ethyl Alcohol 5.000 5.000 Acid Polyacrylic 0.185 — Sodium Citrate, Dihydrate — 0.100 Acid Citric Solution 50% — 0.100 Sodium Dicoctyl  0-0.200 — Sulfosuccinate Silwet L-7600 0-0.2 0.200 Hydrogenated Castor Oil 1.400 1.400 PEG 60 Fragrance  0-1.5% 0-1.5% Malodor Reduction 1.0   0-1.50% Composition (MRC A, B, or C) Hydroxypropyl 0.380 0.380 BetaCyclodextrine Koralone B-119 0.050 0.050 Sodium Hydroxide 20% 0-0.3 — Total 100    100 Silwet L-7600 Organosilicone (available from BASF) Koralone B-119 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water (available from Dow Chemical)

-   A resulting aerosol air freshener is effective at reducing malodor     in the air when sprayed. In addition the aerosol can be sprayed on     fabrics to reduce or prevent malodor.

EXAMPLES 6.1-6.4 Heavy Duty Liquid Composition

-   A HDL-Heavy Duty Liquid composition is prepared with malodor     reduction composition, according to the compositions shown in     Example 1.

Example Example Example Example 6.1 6.2 6.3 6.4 WT % WT % WT % WT % Ingredient Active Active Active Active AE_(1.8)S 16.3 16.3 12 8 C_(11.8) linear alkyl benzene 2.8 2.8 8 — sulfonic acid HSAS 13.6 13.6 0 22 C24 alcohol, EO9 2.2 2.2 1 1.8 Citric Acid 0.9 0.9 2 1.7 Lactic Acid — 5.8 — — C₁₂-C₁₈ Fatty Acid 2.3 1.3 0.8 3.0 Protease (55.3 mg/g) 1.7 1.7 1.7 1.7 Amylase (25.4 mg/g) 0.7 0.7 0.7 0.7 Borax 3.6 3.6 3.6 3.6 Calcium Formate 0.2 0.2 0.2 0.2 Polyethyleneimine 600, 1.6 1.6 — 1.6 EO20 Polyethyleneimine 600, 1.6 — 2.0 1.6 EO24, PO16 DTPA 0.3 0.3 0.3 0.3 Tiron ® 0.8 0.8 0.8 0.8 Optical Brightener [7] 0.3 0.3 0.3 0.3 NaOH 4.0 9.3 4.0 9.3 Na Cumene Sulfonate 1.1 1.1 1.1 1.1 Na Formate 0.2 0.2 0.2 0.2 Aesthetics Dye 0.03-1.0 0.03-1.0 0.03-1.0 0.03-1.0 Perfume  0.5-3.0  0.5-3.0  0.5-3.0  0.5-3.0 Malodor Reducing 0.15-1.0 0.15-1.0 0.15-1.0 0.15-1.0 Composition Water and Solvent Balance Balance Balance Balance pH 5.0 8.0 5.0 8.0 HSAS secondary alkyl sulfate, acid form DTPA diethylene triamine pentaacetic acid (DTPA) Tiron 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate

-   The resulting heavy duty liquid product when used to wash articles     of clothing is effective at reducing malodor on the washed clothing.

EXAMPLES 7.1-7.3 Heavy Duty Liquid Composition

Other examples of HDL—Heavy Duty Liquid composition prepared with malodor reduction composition, according to the compositions shown in Example 1.

Example Example Example 7.1 7.2 7.33 WT % WT % WT % Ingredient Active Active Active AE_(1.8)S 14%  8% 11%   Amine Oxide 2% — — C_(11.8) linear alkyl benzene sulfonic 10%  — — acid HSAS — 20%  15   HF LAS — — — C24 alcohol, EO9 1% 2% 1.2% Citric Acid 3%   1.5% 0.9% C₁₂-C₁₈ Fatty Acid 2% 1% 1.5% Protease (55.3 mg/g)  0.013 0.8  0.013 Amylase (25.4 mg/g)  0.02 0.7 0.02  Borax  2-8.0  2-8.0  2-8.0 Calcium Formate 0.2 0.2 0.2   Carezyme 5.0L 0.01-0.5  — 0.01-0.5  Polyethyleneimine 600, EO20 0.5-3.0 0.5-3.0 0.5-3.0 Polyethyleneimine 600, EO24, 0.5-3.0 — 0.5-3.0 PO16 DTPA 0.1-1.0 0.1-1.0 0.1-1.0 Tiron ® 0.1-1.5 0.1-1.5 0.1-1.5 Optical Brightener 0.1-1.0 0.1-1.0 0.1-1.0 MEA- Hydrogenated Castor Oil 0.5-3.0 — NaOH 0.1-1.0 0.1-1.0 Na Cumene Sulfonate 1.1 — Na Formate 0.2 0.2 Dye 0.1 0.1 Malodor Reducing Composition 0.15-1.0  0.15-1.0  0.15-1.0  Perfume 0.9 0.5-3  Water and Solvent Balance Balance Balance HSAS secondary alkyl sulfate, acid form DTPA diethylene triamine pentaacetic acid (DTPA) Tiron 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate

-   The resulting heavy duty liquid product when used to wash articles     of clothing is effective at reducing malodor on the washed clothing.

EXAMPLES 8.1-8.6 Soluble Uni-Dose Heavy Duty Liquid Composition

-   An example for a Soluble Uni-dose heavy duty liquid composition     prepared with malodor reduction composition, according to the     compositions shown in Example 1.

3 compartments pouched product 8.1 8.2 8.3 8.4 8.5 8.6 Form liquid liquid liquid liquid gel liq liq liq Compartment # 1 1 1 1 1 1 2 3 Dosage (g) 36.0 38.0 32.0 36.0 40.0 34.0 25 35 Alkylbenzene 14.5 13.8 16.0 14.5 13.5 14.5 20.0 sulfonic acid C₁₂₋₁₄ alkyl 8.5 16.4 10.0 8.5 15.0 8.5 ethoxy 3 sulfate C₁₂₋₁₃ alkyl 3- 13.0 ethoxylate C₁₂₋₁₄ alkyl 7- 12.5 9.0 14.0 4.0 12.5 17.0 ethoxylate C12-18 Fatty 14.5 8.5 16.0 15.0 7.2 14.5 13.0 acid Citric acid 2.0 4.1 Enzymes 0-3 0-3 0-3 0-3 0-3 0-3 PAP granule¹ 50.0 Ethoxysulfated 3.0 2.2 Hexamethylene Diamine Dimethyl Quat Ethoxylated 4.0 1.0 4.0 3.0 2.0 Polyethylenimine Hydroxyethane 1.0 1.0 1.6 0.6 0.6 diphosphonic acid Ethylene 1.0 diamine tetra(methylene phosphonic) acid Brightener 0.2 0.2 0.3 0.3 0.2 0.2 0.2 Polydimethyl 3.0 Siloxane Hueing dye² 0.05 Perfume 1.5-2.0 1.5-2.0 1.5-2.0 1.5-2.0 1.5-2.0 1.5-2.0 Malodor 0.3-0.7 0.3-0.7 0.3-0.7 0.3-0.7 0.3-0.7 0.3-0.7 reducing composition Water and To 100% minors Buffers (sodium To pH 8.0 carbonate, monoethanolamine) Solvents (1,2 To 100% propanediol, ethanol), Sulfate ¹PAP granule ²Hueing dye

-   The resulting Unidose pouch product when used to wash articles of     clothing is effective at reducing malodor on the washed clothing.

EXAMPLES 9.1-9.5 Fabric Enhancer Solid Particle or Bead Composition

-   An example of a Fabric Enhancer bead composition prepared with     malodor reduction composition, according to the compositions shown     in Example 1.

Example Example Example Example Example 9.1 9.2 9.3 9.4 9.5 Active Active Active Active Active Ingredients Wt % Wt % Wt % Wt % Wt % PEG 8000 86.21 83.255 83.255 86.21 82.49 Free (Neat) 4.41 5.88 4.41 4.25 5.88 Perfume Malodor 0.75-1.5 0.75-1.5 0.75-1.5 0.75-1.5 0.75-1.5 reducing composition Perfume 5.88 8.22 8.88 5.88 8.70 Micro Cap- sule (PMC) Encapsulated 1.88 1.88 1.88 1.88 1.88 Perfume Malodor 1.47 — 1.47 1.63 — Reducing Composition Encapsulated — 0.75 0.75 — 0.9 Malodor Reducing Composition Aesthetics 0.015 0.015 0.015 0.015 0.015 Dye 1. PMC is a friable PMC with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC (including encapsulated perfume) is assumed. 2. Encapsulated perfume (within PMC) assumes about 32% active

-   The resulting Fabric enhancing bead product when added to an     automatic washing machine is effective at reducing malodor on the     clothing.

EXAMPLES 10.1-10.4 Dryer Added Fabric Softener Sheet Composition

-   An example of a dryer added fabric softener sheet composition     prepared with malodor reduction composition, according to the     compositions shown in Example 1.

Example Example Example Example 10.1 10.2 10.3 10.4 Wt % Wt % Wt % Wt % Ingredient Active Active Active Active DEQA¹ — 50 — — DEQA² 30 — — 30 DTDMAMS³ — — 50 — 7018FA⁴ — — 50 — TS-20⁵ 15 — — 15 SMS⁶ 15 — — 15 SDASA⁷ 19 25 — 19 TPED⁸ — 3 — — Complex⁹ 16.5 16.5 — 8.0 Clay¹⁰ 3 4 — 3 Free (Neat) Perfume 1.5 1.5 — 1.5 Free (Neat) malodor 0.5 0.5 0.5 — reducing compostion Encapsulated Perfume/ — — — 1.56 malodor reducing composition ¹¹ Encapsulated Perfume¹² — 0.4 — — Encap malodor reducing — — — 0.5 composition Active Weight (g/sheet) 2.4 2.4 1.9 2.4 ¹DEQA¹: Di(soft tallowoyloxyethyl)dimethylammonium methyl sulfate with 25%> 7018 FA, as described below, as solvent ²DEQA²: Di(soft tallowoyloxyethyl)hydroxyethylmethylammoniun methyl sulfate with 18% 

 partially hydrogenated tallow fatty acid solvent ³DTDMAMS: Di(hydrogenated tallowalkyl)dimethylammonium methyl sulfate ⁴7018FA: 70:30 Stearic Acid:Palmitic Acid (IV = 0) Industrene 7018 sold by Witco ⁵TS-20: Polyoxyethylene-20 Sorbitan Tristearate (Glycosperse TS-20, sold by Lonza ⁶SMS: Sorbitan Mono Stearate ⁷SDASA: 1:2 ratio of stearyl dimethyl amine:triple pressed stearic acid ⁸TPED: N,N,N′,N′-Tetrakis(2-hydroxypropyl)ethylenediamine (Quadrol, sold by BASF) ⁹Complex: Beta-Cyclodextrin/Perfume Complex ¹⁰Clay: Calcium Bentonite Clay (Bentonite L sold by Southern Clay Products Free (Neat) Perfume ¹¹ PMC is a friable PMC with a urea-formaldehyde shell from Appleton. About 50% water by weight of the PMC (including encapsulated perfume and/or blocker) is assumed. ¹²Encapsulated perfume and encapsulated malodor reducing composition (within PMC) assumes about 32% active

-   The compositions of Example 10 are mixed homogeneously and     impregnated onto a non-woven polyester sheet having dimensions of     about 6% in×12″ (about 17.1 cm×30.5 cm) and weighing about 1 gram. -   The resulting dryer added fabric softener sheet product when added     to an automatic dryer is effective at reducing malodor on the     clothing.

EXAMPLES 11.1-11.4 Liquid Fabric Enhancer Composition

-   An example of a Liquid Fabric Enhancer composition prepared with     malodor reduction composition, according to the compositions shown     in Example 1.

Example Example Example Example 11.1 11.2 11.3 11.4 Wt % Wt % Wt % Wt % Ingredient Active Active Active Active FSA¹ 12 21 18 14 Low MW alcohol 1.95 3.0 3.0 2.28 Structurant^(2,3) 1.25^(e) — 0.2^(f) — Free (Neat) Perfume 1.50 1.8 2.0 1.50 Free (Neat) malodor 0.3 0.7 — — reducing composition Encapsulated Perfume⁴ — 0.6 — 0.6 Encap malodor reducing — — 0.6 0.6 composition⁴ Perfume/malodor — 1.85 1.85 3.7 reducing composition encapsulated⁵ Calcium Chloride 0.10 0.12 0.1 0.45 DTPA⁶ 0.005 0.005 0.005 0.005 Preservative (ppm)⁷ 5 5 5 5 Antifoam⁸ 0.015 0.15 0.11 0.011 Polyethylene imines⁹ 0.15 0.05 — 0.1 Delivery enhancing 0.1 0.1 0.2 0.05 PDMS emulsion¹⁰ — 0.5 1 2.0 Dispersant¹¹ — — 0.5 0.2 Organosiloxane 5 — — — Front-end Stability 0.06¹¹ 0.63¹² 0.36¹¹ 0.14¹² Aid^(12,13) Dye (parts per million 40 11 30 40 ppm) Ammonium Chloride 0.10 Hydrochloric Acid 0.010 0.01 0.10 0.010 Deionized Water Balance Balance Balance Balance ¹N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride. ²Cationic high amylose maize starch-available from National Starch under the trade name HYLON VII ®. ³Cationic polymer available from BASF ® under the name Rheovis ® CDE. ⁴Encapsulated perfume and encapsulated malodor reducing composition (within PMC) assumes about 32% active ⁵PMC is a friable PMC with a urea-formaldehyde shell from Appleton. About 50% water by weight of the PMC (including encapsulated perfume and/or malodor reducing composition) is assumed. ⁶Diethylene triamine pentaacetic acid ⁷19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water available from Dow Chemical under the trade name Koralone B-119 ⁸Silicone antifoam agent available from Dow Corning ® under the trade name DC2310. ⁹Polyethylene imines available from BASF under the trade name Lupasol ®. ¹⁰Polydimethylsiloxane emulsion from Dow Corning ® under the trade name DC346. ¹¹Non-ionic such as TWEEN 20 ™ or cationic surfactant as Berol 648 and Ethoquad ® C 25 from Akzo Nobel. ¹²Organosiloxane polymer condensate made by reacting hexamethylenediisocyanate (HDI), and a, w silicone diol and 1,3-propanediamine, N′-(3-(dimethylamino)propyl)-N,N-dimethyl- Jeffcat Z130) or N-(3-dimethylaminopropyl)-N,Ndiisopropanolamine (Jeffcat ZR50) commercially available from Wacker Silicones, Munich, Germany. ¹³Fineoxocol ® 180 from Nissan Chemical Co. ¹⁴Isofol ® 16 from Sasol. **For example PGE

Examples 11.1 to 11.4 are made by combining the molten fabric softener active with the front-end stability agent to form a first mixture. This first mixture is combined with water and hydrochloric acid using a high shear mixing device to form a second mixture. The adjunct ingredients are combined with the second mixture using low shear mixing to form the fabric enhancing formula.

Examples 11.1 through 11.4 are used by dosing 10 to 60 g of the formula into the rinse liquor for example via dispensing into a clothes washing machine. Clothes are dried on a line or in an automated clothes dryer. The fabrics treated with these formulas have improved feel and scent and are effective at reducing malodor on the clothing.

EXAMPLE 12.1-12.2 Spray-Dried Laundry Detergent Powder Composition and Process of Making It

-   An example of a Spray-Dried Laundry Detergent Powder composition     prepared with malodor reduction composition, according to the     compositions shown in Example 1.

Dried Dried Slurry Powder Slurry Powder 12.1 12.1 12.2 12.2 Compositions w/w % w/w % w/w % w/w % Linear alkyl benzene sulfonate 10.6 15.8 21.3 35.7 Acrylate/maleate copolymer 4.6 6.8 9.4 14.2 Ethylenediame disuccinic acid 1.4 2.1 1.7 2.9 and/or Hydroxyethane dimethylene phosphonic acid Sodium carbonate 19.4 26.5 18.8 29.9 Sodium sulfate 28.6 42.4 — — Carboxy methyl cellulose polymer — — 4.3 7.1 Miscellaneous, such as magnesium 1.4 2.2 2.5 4.2 sulfate, brightener and one or more stabilizers Free (Neat) Perfume (spray-on) — 1.7 — 2.4 Free (Neat) malodor reduction — 0.5 — 0.6 composition (spray-on) Water 34.0 2.0 42.0 3.0

Preparation of Spray-Dried Laundry Detergent Powders.

-   Aqueous slurry 12.1 having the composition as described above is     prepared having a moisture content of 34.0%. Any ingredient added     above in liquid form is heated to 70° C., such that the aqueous     slurry is never at a temperature below 70° C. At the end of     preparation, the aqueous slurry is heated to 80° C. and pumped under     pressure (5×10⁶ Nm⁻²), into a counter current spray-drying tower     with an air inlet temperature of from 290° C. The aqueous slurry is     atomized and the atomized slurry is dried to produce a solid     mixture, which is then cooled and sieved to remove oversize material     (>1.8 mm) to form a spray-dried powder, which is free-flowing. Fine     material (<0.15 mm) is elutriated with the exhaust the exhaust air     in the spray-drying tower and collected in a post tower containment     system. The spray-dried powder 12.1 has a moisture content of 2.0 wt     %, a bulk density of 310 g/l and a particle size distribution such     that greater than 90 wt % of the spray-dried powder has a particle     size of from 150 to 710 micrometers. The composition of the     spray-dried powder 12.1 is listed in the table above. Perfume and     malodor reduction composition are sprayed onto the composition     following the spray dry procedure. -   Aqueous slurry 12.2 having the composition as described above is     prepared having a moisture content of 42.0%. Any ingredient added     above in liquid form is heated to 70° C., such that the aqueous     slurry is never at a temperature below 70° C. At the end of     preparation, the aqueous slurry is heated to 85° C. and pumped under     pressure (from 6.5×10⁶ Nm⁻²), into a counter current spray-drying     tower with an air inlet temperature of from 275° C. The aqueous     slurry is atomized and the atomized slurry is dried to produce a     solid mixture, which is then cooled and sieved to remove oversize     material (>1.8 mm) to form a spray-dried powder 12.2, which is     free-flowing. Fine material (<0.15 mm) is elutriated with the     exhaust the exhaust air in the spray-drying tower and collected in a     post tower containment system. The spray-dried powder has a moisture     content of 3.0 wt %, a bulk density of 250 g/l and a particle size     distribution such that greater than 90 wt % of the spray-dried     powder has a particle size of from 150 to 710 micrometers. The     composition of the spray-dried powder is given in the table above.     Perfume and malodor reduction composition are sprayed onto the     composition after the spray dry process.

EXAMPLE 13 Plastic Film Example with Malodor Reducing Composition

-   A plastic film is treated with an Malodor Reduction Composition     disclosed in the present specification. Said treatment is     accomplished by spraying said Malodor Reduction Composition on the     film. Said Malodor Reduction Composition is applied to at a level of     0.1% to 5% based on weight of the film. The Malodor Reduction     Composition is found on the surface and may also be absorbed into     the plastic film.

EXAMPLE 14 Diaper Example with Malodor Reducing Composition

-   A diaper article, is treated with a Malodor Reduction Composition     disclosed in the present specification. The Malodor Reduction     Composition is disposed on one or more areas such as:     -   the garment-facing side;     -   the body-facing side of the topsheet;     -   the absorbent core;     -   the body-facing side of the backsheet. -   The Malodor Reduction Composition may also be disposed on the     garment-facing side of the absorbent core and/or on other components     such as the garment facing side of a nonwoven dusting layer or     body-facing side of a secondary topsheet or acquisition layer. In     some embodiments, a topsheet or an acquisition layer may comprise a     tissue layer and/or a nonwoven layer, and the malodor reduction     composition may be disposed on either the tissue layer or the     nonwoven layer. As discussed below, the Malodor Reduction     Composition may be in the absorbent article via incorporation into     an adhesive. In some embodiments, the Malodor Reduction Composition     may be incorporated into the absorbent article via a lotion that is     applied to a substrate component of the article. In some     embodiments, the malodor reduction composition may be incorporated     into the absorbent article via an elastomeric film. In some     embodiments, the malodor reduction composition may be in an article     by having been incorporated into the making of an article component,     including, but not limited to, a film, a nonwoven, AGM, elastics,     and/or ink.

EXAMPLE 16.1-16.5 Deodorant Example with Malodor Reducing Composition

-   An example of Deodorant compositions prepared with malodor reduction     composition, according to the compositions shown in Example 1.

Ingredient 16.1 16.2 16.3 16.4 16.5 Product Form Solid Solid Solid Solid Aerosol Deodor- Deodor- Deodor- Deodor- Deodor- ant ant ant ant ant or Control Body Spray dipropylene glycol 48 48 20 30 20 propylene glycol 19.3 19.3 22 — — tripopylene glycol — — 25 — — Glycerine — — — 10 — PEG -8 — — — 20 — Propylene Glycol 3 1.4 1.4 — — — Myristyl Ether ethanol — — — — QS Water QS QS QS QS — sodium stearate 5.4 5.4 5.5 5.5 — tetra sodium EDTA 0.5 0.5 0.05 0.05 — sodium hydroxide — — 0.04 0.04 — triclosan — — 0.3 0.3 — Neat Perfume 2.8 2.8 2 1.5 1.5 Malodor reducing — 0.7 1.0 0.5 0.35 composition Blue 1 0.0009 0.0009 — — — Propellant (1,1 — — — — 40 difluoroethane) QS - Indicates that this material is used to bring the total to 100%.

EXAMPLES 17.1-17.3 Body Wash with Malodor Reducing Composition

-   An example of Body Wash compositions prepared with malodor reduction     composition, according to the compositions shown in Example 1.

17.1 Body 17.2Body 17.3Body Wash Wash Wash Sodium Laureth-3 Sulfate (as 28% 27.85% 27.85% 27.85% active) Water Q.S. Q.S. Q.S. Sodium Lauryl Sulfate (as 29% 10.34 10.34 10.34 active) Cocamidopropyl Betaine B (30% 4.01 4.01 4.01 active) Citric Acid 0.18 0.18 0.18 Sodium Benzoate 0.3 0.3 0.3 Disodium EDTA 0.12 0.12 0.12 Methylchloroisothiazolinone/ 0.04 0.04 0.04 Methylisothiazolinone Sodium Chloride 2.35 1.7 1.6 Neat Perfume 1.25 1 2 Malodor reducing composition 0.25 0.175 0.25 QS - indicates that this material is used to bring the total to 100%.

EXAMPLES 18.1-18.6 Antiperspirant Examples with Malodor Reducing Composition

-   An example of Antiperspirant compositions prepared with malodor     reduction composition, according to the compositions shown in     Example 1.

18.1 18.2 18.3 18.4 18.5 18.6 Invisible Invisible Invisible Soft Soft Soft Solid Solid Solid Solid Solid Solid Aluminum 24 24 24 26.5 26.5 26.5 Zirconium Trichlorohydrex Glycine Powder Cyclopentasiloxane Q.S Q.S. Q.S. Q.S. Q.S. Q.S. Dimethicone — — — 5 5 5 CO-1897 Stearyl 14 14 14 — — — Alcohol NF Hydrogenated 3.85 3.85 3.85 — — — Castor Oil MP80 Deodorized Behenyl Alcohol 0.2 0.2 0.2 — — — Tribehenin — — — 4.5 4.5 4.5 C 18-36 acid — — — 1.125 1.125 1.125 triglyceride C12-15 Alkyl 9.5 9.5 5 — — — Benzoate PPG-14 Butyl 6.5 6.5 — 0.5 0.5 0.5 Ether Phenyl 3 — 3 — — — Trimethicone White Petrolatum 3 — — 3 3 3 Mineral Oil 1.0 1.0 1.0 — — — Free (Neat) 1.0 0.75 2.0 0.75 1.0 1.25 Perfume Malodor reducing 0.25 — 0.35 0.175 0.25 0.1 composition Beta-Cyclodextrin — 3.0 — — — 3.0 complexed with Malodor reducing composition Talc Imperial 250 3.0 3.0 3.0 — — — USP Polyacrylate — — 1.9 — — — Microcapsule loaded with Malodor reducing composition QS - indicates that this material is used to bring the total to 100%.

EXAMPLE 19.1-19.4 Dish Cleansing Composition Examples with Malodor Reducing Composition

-   An example of Dish cleaning compositions prepared with malodor     reduction composition, according to the compositions shown in     Example 1.

19.1 19.2 19.3 19.4 Alkyl C₁₀₋₁₄ Ethoxy 26.9 — — 25.7 Sulphate (AE0.6S) Alkyl C₁₀₋₁₄ Ethoxy — 18.7 26.9 — Sulphate (AE2S) Sodium alkyl benzene — 8.0 — — sulfonate C12-14 dimethyl amine 6.1 — — 4.1 oxide Cocamido propyl betaine — 4.5 6.8 3.2 Branched Nonionic: 1.0 0.8 — — 3-propyl heptanol EO8 PEI600-EO10-PO7 — — 0.8 — block polymer Perfume 0.15-0.3  0.15-0.3  0.15-0.3  0.15-0.3  Malodor Reducing 0.06-0.15 0.06-0.15 0.06-0.15 0.06-0.15 Composition Ethanol 4.0 5.0 3.0 3.0 Polypropylene glycol 1.1 0.8 1.1 1.1 MW2000 Sodium Chloride 1.3 0.8 1.3 0.5 Minors* and water to balance up to 100%

EXAMPLES 20.1-20.4 Heavy Duty Liquid Composition

-   A HDL-Heavy Duty Liquid composition is prepared with malodor     reduction composition, according to the compositions shown in     Example 1.

Example Example Example Example 20.1 20.2 20.3 20.4 WT % WT % WT % WT % Ingredient Active Active Active Active AE_(1.8)S 16 16 12 8 C_(11.8) linear alkyl benzene 3 3 8 — sulfonic acid HSAS¹ 14 14 0 22 C24 alcohol, EO9 2 2 1 2 Citric Acid 1 1 2 2 Lactic Acid — 6 — — C₁₂-C₁₈ Fatty Acid 2 1 1 3 Protease (55.3 mg/g) 2 2 2 2 Amylase (25.4 mg/g) 0.7 0.7 0.7 0.7 Borax 3.6 3.6 3.6 3.6 Calcium Formate 0.2 0.2 0.2 0.2 Polyethyleneimine 600, 1.6 1.6 — 1.6 EO20 Polyethyleneimine 600, 1.6 — 2.0 1.6 EO24, PO16 DTPA² 0.3 0.3 0.3 0.3 Tiron ®³ 0.8 0.8 0.8 0.8 Optical Brightener 0.3 0.3 0.3 0.3 NaOH 4 9 4 9 Na Cumene Sulfonate 1 1 1 1 Na Formate 0.2 0.2 0.2 0.2 Aesthetics Dye 0.03-1  0.03-1  0.03-1  0.03-1  Perfume 0.5-3 0.5-3 0.5-3 0.5-3 Malodor Reducing 0.1-1 0.1-1 0.1-1 0.1-1 Composition Water and Solvent Balance Balance Balance Balance pH 5 8 5 8

-   The resulting heavy duty liquid product when used to wash articles     of clothing is effective at reducing malodor on the washed clothing.

EXAMPLES 21.1-21.3 Heavy Duty Liquid Composition

Other examples of HDL-Heavy Duty Liquid composition prepared with malodor reduction composition, according to the compositions shown in Example 1.

Example Example Example 21.1 21.2 21.3 WT % WT % WT % Ingredient Active Active Active AE_(1.8)S 14   8   11   Amine Oxide 2   — — C_(11.8) linear alkyl benzene sulfonic 10%  — — acid HSAS¹ — 20   15   C24 alcohol, EO9  1-2  1-2  1-2 Citric Acid 0.5-3 0.5-3 0.5-3 C₁₂-C₁₈ Fatty Acid  1-2  1-2  1-2 Protease (55.3 mg/g) 0.013-0.8  0.013-0.8  0.013-0.8  Amylase (25.4 mg/g)  0.02-0.7  0.02-0.7  0.02-0.7 Borax  2-8  2-8  2-8 Calcium Formate 0.2 0.2 0.2 Carezyme 5.0L  0.01-0.5 —  0.01-0.5 Polyethyleneimine 600, EO20 0.5-3 0.5-3 0.5-3 Polyethyleneimine 600, EO24, 0.5-3 — 0.5-3 PO16 DTPA² 0.1-1 0.1-1 0.1-1 Tiron ® ³ 0.1-2 0.1-2 0.1-2 Optical Brightener 0.1-1 0.1-1 0.1-1 MEA - Hydrogenated Castor Oil 0.5-3 0.5-3 NaOH 0.1-1 0.1-1 0.1-1 Na Cumene Sulfonate 1.1 — — Na Formate 0.2 0.2 0.2 Dye 0.1 0.1 0.1 Malodor Reducing Composition  0.15-1.0 —  0.15-1.0 Encapsulated Malodor Reducing⁴ — 0.3-3 — Perfume 0.5-2 0.5-2 — Encapsulated Perfume⁴ — — 1.5-3 Water and Solvent Balance Balance Balance ¹HSAS is secondary alkyl sulfate, acid form ²DTPA is diethylene triamine pentaacetic acid (DTPA) ³ Tiron is 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate ⁴Encapsulated perfume and encapsulated malodor reducing composition is a slurry. One non-limiting example of an encapsulate is a friable microcapsule with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC (including encapsulated perfume) is assumed.

-   The resulting heavy duty liquid product when used to wash articles     of clothing is effective at reducing malodor on the washed clothing.

EXAMPLES 22.1-22.3 Fabric Enhancer Solid Particle or Bead Composition

-   An example of a Fabric Enhancer bead composition prepared with     malodor reduction composition, according to the compositions shown     in Example 1.

Example Example Example 22.1 22.2 22.3 Active Active Active Ingredients Wt % Wt % Wt % PEG 8000 80-90 80-90 80-90 Free (Neat) Perfume 3.5-6  4-6 3-5 Malodor reducing composition 0.5-2  0.5-2  0.5-2  Encapsulated Perfume ¹ 0-2 0-2 2-3 Encapsulated Malodor Reducing — 0.5-2  — Composition ¹ Dipropylene Glycol 0-6 0-5  0-4.5 Aesthetics Dye 0.015 0.015 0.015

-   -   3. Encapsulated perfume and encapsulated malodor reducing         composition is a slurry. One non-limiting example of an         encapsulate is a friable microcapsule with a urea-formaldehyde         shell from Appvion-Encapsys. About 50% water by weight of the         PMC (including encapsulated perfume) is assumed.

-   The resulting Fabric enhancing bead product when added to an     automatic washing machine is effective at reducing malodor on the     clothing.

EXAMPLE: 23.1-23.6 Malodor Reduction Composition

-   The following malodor reduction malodor reduction compositions are     made by combining the listed ingredients. All ingredients are in     weight percent of the total malodor reduction composition.

Ingredient CAS# 23.1 23.2 23.3 23.4 23.5 23.6 (3aR,5aS,9aS,9bR)- 6790-58-5 0.1 0.5 0 0 0.5 0.2 3a,6,6,9a-tetramethyl- 2,4,5,5a,7,8,9,9b- octahydro-1H- benzo[e][1]benzofuran 7-(3-methylbutyl)-1,5- 362467-67-2 1 0.5 0.07 0.6 0.01 0 benzodioxepin-3-one triethyl 2- 77-93-0 0.05 0.2 1 0.5 0.09 0.03 hydroxypropane-1,2,3- tricarboxylate 1,1,2,3,3-pentamethyl- 33704-61-9 1 1 0.5 0.5 0.2 0.2 2,5,6,7-tetrahydroinden-4- one (3R,3aS,6S,7R,8aS)- 19870-74-7 2 1 0 2 1 3 octahydro-6-methoxy- 3,6,8,8-tetramethyl-1H- 3a,7-methanoazulene (5E)-3- 63314-79-4 0.3 0.2 0.43 0 0.15 0.17 methylcyclopentadec-5- en-1-one 4-(octahydro-4,7- 30168-23-1 0.5 1 0.7 1 0.2 0.4 methano-5H-inden-5- ylidene)butanal 3a,4,5,6,7,7a-hexahydro- 5413-60-5 3 1 0.5 0.5 1 0.8 4,7-methanoinden-6-yl acetate 3a,4,5,6,7,7a-hexahydro- 68912-13-0 4 0.8 2 2 0.5 1 1H-4,7-methanoinden-1-yl propanoate 5-(diethoxymethyl)-1,3- 40527-42-2 0.7 0.5 0 0 1 0 benzodioxole 1,3,4,6,7,8-hexahydro- 1222-05-5 5 8 3 8 10 5 4,6,6,7,8,8- hexamethylcyclopenta(g)- 2-benzopyran 1-(2,3,8,8-tetramethyl- 54464-57-2 18 25 54 28 20 50 1,3,4,5,6,7- hexahydronaphthalen-2- yl)ethanone 2,2,7,7- 23787-90-8 0.6 0.5 0.5 3 1 0 tetramethyltricyclo[6.2.1.0 1,6]undecan-5-one [(1R,2S)-1-methyl-2- 198404-98-7 0.05 0.5 0 0.18 0.05 0.1 [[(1R,3S,5S)-1,2,2- trimethyl-3- bicyclo[3.1.0]hexanyl]methyl]cyclopropyl]methanol 2,4-dimethyl-4,4a,5,9b- 27606-09-3 40 38 26 26 20 10 tetrahydroindeno[1,2- d][1,3]dioxine methyl 3-oxo-2- 24851-98-7 15 7 5 15 22 22 pentylcyclopentaneacetate 2-[2-(4-methyl-1- 95962-14-4 5 7 5 10 16 5 cyclohex-3- enyl)propyl]cyclopentan- 1-one 2,2- 101-48-4 0.4 1 0.5 1 1 0 dimethoxyethylbenzene (E)-3,3-dimethyl-5-(2,2,3- 107898-54-4 0.2 1 0 0.7 0.2 1 trimethyl-3-cyclopenten- 1-yl)-4-penten-2-ol octahydro-5-methoxy-4,7- 86803-90-9 0.1 0.3 0.3 0.02 0.1 0.1 methano-1H-indene-2- carboxaldehyde 1-oxacycloheptadecan-2- 109-29-5 & 3 5 0.5 1 5 1 one & 502-72-7 cyclopentadecanone TOTAL 100 100 100 100 100 100

-   Each of the malodor reduction compositions of Examples 23.1 through     23.6 is used in a consumer product by combining the malodor     reduction composition at a level of about 0.05% to about 0.35%,     based on total consumer product weight, with the consumer product.     Then the consumer product is applied to a site on the human body     that is in need of malodor reduction. In one aspect, the consumer     product is selected from a shampoo, body wash, conditioner and an     antiperspirant/deodorant.

EXAMPLES 24.1-24.6 Malodor Reduction Composition

-   The following malodor reduction malodor reduction compositions are     made by combining the listed ingredients. All ingredients are in     weight percent of the total malodor reduction composition.

Ingredient CAS # 24.1 24.2 24.3 24.4 24.5 24.6 (E)-1-(2,6,6-trimethyl-1- 127-42-4 4 8 2 8 3 2 cyclohex-2-enyl)pent-1- en-3-one ethyl dodecanoate 106- 0 1 0 3 0 0 33-2 3a,4,5,6,7,7a-hexahydro- 68912- 8 30 1 4 1 3.5 1H-4,7-methanoinden-1- 13-0 yl propanoate [1R- 1139- 0 0.3 2 .5 0 0.5 (1R*,4R*,6R*,10S*)]- 30-6 4,12,12-trimethyl-9- methylene-5- oxatricyclo[8.2.0.04,6]dodecane (8E)-cyclohexadec-8-en- 3100- 0 5 0 7 0 0 1-one 36-5 3,5,5-trimethylhexyl 58430- 25 15 50 35 60 56 acetate 94-7 ethyl (2,3,6- 93981- 0 1 0 5 0 0 trimethylcyclohexyl) 50-1 carbonate 2,4-dimethyl-4,4a,5,9b- 27606- 25 10 15 15 16 15 tetrahydroindeno[1,2- 09-3 d][1,3]dioxine 2,2,7,7- 23787- 8 9 5 7 5 5 tetramethyltricyclo[6.2.1.01, 90-8 6]undecan-5-one (3,5-dimethylcyclohex-3- 67634- 0 0.7 0 .5 0 0 en-1-yl)methanol 16-6 3-(7,7-dimethyl-4- 33885- 30 20 25 15 15 18 bicyclo[3.1.1]hept-3- 52-8 enyl)-2,2- dimethylpropanal Total 100 100 100 100 100 100

-   Each of the malodor reduction compositions of Examples 24.1 through     24.6 is used as a perfume component in an air care device at a level     of form about 5% to about 100% or in other consumer products by     combining the malodor reduction composition at a level of about     0.0003% to about 5% based on total consumer product weight, with the     consumer product. Then the consumer product is applied to a site on     the human body that is in need of malodor reduction, used in an air     care device and/or as a treatment composition to treat a fabric     and/or hard surface. In one aspect, the consumer product is selected     from a shampoo, body wash, conditioner, an antiperspirant/deodorant     and/or a fabric or hard surface cleaner or treatment composition     such as a detergent or fabric enhancer.

The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”

Every document cited herein, including any cross referenced or related patent or application, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests, or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.

While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is, therefore, intended to cover in the appended claims all such changes and modifications that are within the scope of this invention. 

What is claimed:
 1. A malodor reduction composition comprising, based on total malodor reduction composition weight: a) from about 2% to about 8% (E)-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)pent-1-en-3-one; b) from about 0% to about 3% ethyl dodecanoate; c) from about 1% to about 30% 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-1-yl propanoate; d) from about 0% to about 2% [1R-(1R*,4R*,6R*,10S*)]-4,12,12-trimethyl-9-methylene-5-oxatricyclo[8.2.0.04,6]dodecane; e) from about 0% to about 7% (8E)-cyclohexadec-8-en-1-one; f) from about 15% to about 60% 3,5,5-trimethylhexyl acetate; g) from about 0% to about 5% ethyl (2,3,6-trimethylcyclohexyl) carbonate; h) from about 10% to about 25% 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; i) from about 5% to about 9% 2,2,7,7-tetramethyltricyclo[6.2.1.01,6]undecan-5-one; j) from about 0% to about 0.7% (3,5-dimethylcyclohex-3-en-1-yl)methanol; and k) from about 15% to about 30% 3-(7,7-dimethyl-4-bicyclo[3.1.1]hept-3-enyl)-2,2-dimethylpropanal with the proviso that the sum of the elements a) through k) does not exceed 100%.
 2. A malodor reduction composition according to claim 1 comprising from about 0.3% to about 2% [1R-(1R*,4R*,6R*,10S*)]-4,12,12-trimethyl-9-methylene-5 oxatricyclo[8.2.0.04,6]dodecane.
 3. A malodor reduction composition comprising, based on total composition weight, from 0.0001% to 100% of a malodor reduction composition according to claim 1 and an adjunct material, said composition being a consumer product.
 4. A malodor reduction composition according to claim 3 wherein said adjunct material is selected from the group consisting of surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments, fabric softener actives and mixtures thereof.
 5. A malodor reduction composition comprising, based on total composition weight, from 0.0001% to 100% of a malodor reduction composition according to claim 2 and an adjunct material, said composition being a consumer product.
 6. A malodor reduction composition according to claim 5 wherein said adjunct material is selected from the group consisting of surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments, fabric softener actives and mixtures thereof.
 7. A plastic film said plastic film comprising linear low-density polyethylene, low-density polyethylene, high-density polyethylene, and/or compostable film and a malodor reduction composition according to claim
 1. 8. A plastic film said plastic film comprising linear low-density polyethylene, low-density polyethylene, high-density polyethylene, and/or compostable film and a malodor reduction composition according to claim
 2. 9. A method of controlling malodors comprising contacting a material comprising a malodor with a malodor reduction composition according to claim
 1. 10. A method of controlling malodors comprising contacting a material comprising a malodor with a malodor reduction composition according to claim
 2. 11. A method of determining the material's ability to decrease or even eliminate the perception of one or more malodors comprising determining the MORV and/or Universal MORV of said material. 